Purification of terbium by means of argon and hydrogen plasma arc melting | |
Li, Guoling ; Guo, Heng ; Li, Li ; Wang, Chongyun ; Zheng, Jie ; Tian, Wenhuai ; Li, Heping ; Li, Xingguo | |
刊名 | JOURNAL OF ALLOYS AND COMPOUNDS |
2016 | |
关键词 | Rare earth alloys and compounds Plasma arc melting Purification of terbium Computer simulations TB THERMODYNAMICS IMPURITIES KINETICS REMOVAL METAL GD |
DOI | 10.1016/j.jallcom.2015.10.180 |
英文摘要 | The refining of terbium (Tb) by plasma arc melting using pure Ar and Ar + H-2 mixture was examined, respectively. The temperature distribution and gas flow of the plasma arc during the melting process were simulated. The residual metallic impurities were examined by inductively coupled plasma-atomic emission spectrometer. Experimental results show that both methods of argon plasma arc melting (APAM) and hydrogen-argon plasma arc melting (HAPAM) can lead to a good removal of metallic impurities despite of high initial concentrations. HAPAM displays a better refining effect of Tb metal. Activated hydrogen atoms dissociated in high temperature plasma arc, bringing on special chemical interactions, are supposed to be the cause for the wonderful refining effect. The detailed behaviors of impurities and hydrogen atoms are discussed systematically in this study. (C) 2015 Elsevier B.V. All rights reserved.; SCI(E); EI; ARTICLE; liheping@mail.tsinghua.edu.cn; xgli@pku.edu.cn; 1-7; 659 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/437657] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Guoling,Guo, Heng,Li, Li,et al. Purification of terbium by means of argon and hydrogen plasma arc melting[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2016. |
APA | Li, Guoling.,Guo, Heng.,Li, Li.,Wang, Chongyun.,Zheng, Jie.,...&Li, Xingguo.(2016).Purification of terbium by means of argon and hydrogen plasma arc melting.JOURNAL OF ALLOYS AND COMPOUNDS. |
MLA | Li, Guoling,et al."Purification of terbium by means of argon and hydrogen plasma arc melting".JOURNAL OF ALLOYS AND COMPOUNDS (2016). |
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