Chain length dependent alkane/beta-cyclodextrin nonamphiphilic supramolecular building blocks | |
Zhou, Chengcheng ; Huang, Jianbin ; Yan, Yun | |
刊名 | SOFT MATTER
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2016 | |
关键词 | SELF-ASSEMBLING STRUCTURES BETA-CYCLODEXTRIN INCLUSION COMPLEXES AQUEOUS-SOLUTION DOUBLE-BONDS VESICLES AMPHIPHILES DRUG SYSTEMS POLYMERSOMES |
DOI | 10.1039/c5sm02698a |
英文摘要 | In this work we report the chain length dependent behavior of the nonamphiphilic supramolecular building blocks based on the host-guest inclusion complexes of alkanes and b-cyclodextrins (b-CD). H-1 NMR, ESI-MS, and SAXS measurements verified that upon increasing the chain length of alkanes, the building blocks for vesicle formation changed from channel type 2alkane@2 beta-CD via channel type alkane@2 beta-CD to non-channel type 2alkane@2 beta-CD. FT-IR and TGA experiments indicated that hydrogen bonding is the extensive driving force for vesicle formation. It revealed that water molecules are involved in vesicle formation in the form of structural water. Upon changing the chain length, the average number of water molecules associated with per building block is about 16-21, depending on the chain length.; Natural Science Foundation of China [21173011, 21273013, 21473005, 21422302]; National Basic Research Program of China [2013CB933800]; SCI(E); EI; PubMed; ARTICLE; jbhuang@pku.edu.cn; yunyan@pku.edu.cn; 5; 1579-1585; 12 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/435905] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhou, Chengcheng,Huang, Jianbin,Yan, Yun. Chain length dependent alkane/beta-cyclodextrin nonamphiphilic supramolecular building blocks[J]. SOFT MATTER,2016. |
APA | Zhou, Chengcheng,Huang, Jianbin,&Yan, Yun.(2016).Chain length dependent alkane/beta-cyclodextrin nonamphiphilic supramolecular building blocks.SOFT MATTER. |
MLA | Zhou, Chengcheng,et al."Chain length dependent alkane/beta-cyclodextrin nonamphiphilic supramolecular building blocks".SOFT MATTER (2016). |
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