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Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline
Wang, Xiaojuan ; Zou, Leran ; Fu, He ; Xiong, Yifu ; Tao, Zixu ; Zheng, Jie ; Li, Xingguo
刊名ACS APPLIED MATERIALS & INTERFACES
2016
关键词polyaniline Prussian blue oxygen reduction electrocatalysts porous carbon MEMBRANE FUEL-CELLS DENSITY-FUNCTIONAL THEORY IRON-BASED CATALYSTS FE/N/C-CATALYSTS MESOPOROUS CARBONS ORGANIC FRAMEWORKS ELECTROCATALYSTS CATHODE CO ENERGY
DOI10.1021/acsami.5b12102
英文摘要A highly efficient noble-metal-free catalyst for the oxygen reduction reaction (ORR) is derived from a composite of polyaniline (PANI) and Prussian blue analogue (PBA, Co-3[Fe(CN)(6)](2)) by pyrolysis. The composite consists of 2-5 nm PBA nanocrystals homogeneously dispersed in PANI. During the pyrolysis, the PBA nanocrystals serve as both the template for the pore formation and the precursor for the ORR active sites, which results in a nanoporous structure strongly coupled with the ORR active sites. The catalyst exhibits superior ORR performance in both alkaline and acidic electrolyte, comparable to that of the commercial Pt/C with 20 wt % Pt loading.; MOST of China [2012CBA01207]; NSFC [U1201241, 11375020, 51431001, 21321001]; SCI(E); EI; PubMed; ARTICLE; zhengjie@pku.edu.cn; xgli@pku.edu.cn; 13; 8436-8444; 8
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/434649]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Wang, Xiaojuan,Zou, Leran,Fu, He,et al. Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline[J]. ACS APPLIED MATERIALS & INTERFACES,2016.
APA Wang, Xiaojuan.,Zou, Leran.,Fu, He.,Xiong, Yifu.,Tao, Zixu.,...&Li, Xingguo.(2016).Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline.ACS APPLIED MATERIALS & INTERFACES.
MLA Wang, Xiaojuan,et al."Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline".ACS APPLIED MATERIALS & INTERFACES (2016).
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