Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline | |
Wang, Xiaojuan ; Zou, Leran ; Fu, He ; Xiong, Yifu ; Tao, Zixu ; Zheng, Jie ; Li, Xingguo | |
刊名 | ACS APPLIED MATERIALS & INTERFACES |
2016 | |
关键词 | polyaniline Prussian blue oxygen reduction electrocatalysts porous carbon MEMBRANE FUEL-CELLS DENSITY-FUNCTIONAL THEORY IRON-BASED CATALYSTS FE/N/C-CATALYSTS MESOPOROUS CARBONS ORGANIC FRAMEWORKS ELECTROCATALYSTS CATHODE CO ENERGY |
DOI | 10.1021/acsami.5b12102 |
英文摘要 | A highly efficient noble-metal-free catalyst for the oxygen reduction reaction (ORR) is derived from a composite of polyaniline (PANI) and Prussian blue analogue (PBA, Co-3[Fe(CN)(6)](2)) by pyrolysis. The composite consists of 2-5 nm PBA nanocrystals homogeneously dispersed in PANI. During the pyrolysis, the PBA nanocrystals serve as both the template for the pore formation and the precursor for the ORR active sites, which results in a nanoporous structure strongly coupled with the ORR active sites. The catalyst exhibits superior ORR performance in both alkaline and acidic electrolyte, comparable to that of the commercial Pt/C with 20 wt % Pt loading.; MOST of China [2012CBA01207]; NSFC [U1201241, 11375020, 51431001, 21321001]; SCI(E); EI; PubMed; ARTICLE; zhengjie@pku.edu.cn; xgli@pku.edu.cn; 13; 8436-8444; 8 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/434649] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wang, Xiaojuan,Zou, Leran,Fu, He,et al. Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline[J]. ACS APPLIED MATERIALS & INTERFACES,2016. |
APA | Wang, Xiaojuan.,Zou, Leran.,Fu, He.,Xiong, Yifu.,Tao, Zixu.,...&Li, Xingguo.(2016).Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline.ACS APPLIED MATERIALS & INTERFACES. |
MLA | Wang, Xiaojuan,et al."Noble Metal-Free Oxygen Reduction Reaction Catalysts Derived from Prussian Blue Nanocrystals Dispersed in Polyaniline".ACS APPLIED MATERIALS & INTERFACES (2016). |
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