C-O/C-H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative   Ni/Cu Catalysis

doi:10.1021/acs.orglett.6b00819

CORC > 北京大学 > 化学与分子工程学院

	C-O/C-H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis
	Wang, Yang ; Wu, Song-Bai ; Shi, Wen-Juan ; Shi, Zhang-Jie
刊名	ORGANIC LETTERS
	2016
关键词	ELECTRON-DEFICIENT POLYFLUOROARENES DIRECT ARYLATION BOND FORMATION ALLYLIC ALKYLATION PHENOL DERIVATIVES TRANSITION-METAL O BONDS ACTIVATION CLEAVAGE ETHERS
DOI	10.1021/acs.orglett.6b00819
英文摘要	Cross-coupling of polyfluoroarenes with aryl carbamates through the cleavage of both sp(2) C-O and C-H bonds is reported, The reaction conditions are simple, and only transition-metal catalysts and ligands are essential. Mechanistic studies indicated that Ni catalyst played an important role in activating C-O bond, while the Cu one in activating C-H Bond. The developed system proved to be effective for cross-coupling of terminal alkynes with aryl carbamates.; "973" Project from the MOST of China [2013CB228102, 2015CB856600]; NSFC [21431008]; SCI(E); PubMed; ARTICLE; zshi@pku.edu.cn; 11; 2548-2551; 18
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/433650]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Yang,Wu, Song-Bai,Shi, Wen-Juan,et al. C-O/C-H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis[J]. ORGANIC LETTERS,2016.
APA	Wang, Yang,Wu, Song-Bai,Shi, Wen-Juan,&Shi, Zhang-Jie.(2016).C-O/C-H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis.ORGANIC LETTERS.
MLA	Wang, Yang,et al."C-O/C-H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis".ORGANIC LETTERS (2016).