Does the thermal evolution of molecular structures critically affect the   magnetic anisotropy?

doi:10.1039/c5sc01245g

CORC > 北京大学 > 化学与分子工程学院

	Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?
	Qian, Kang ; Baldovi, Jose J. ; Jiang, Shang-Da ; Gaita-Arino, Alejandro ; Zhang, Yi-Quan ; Overgaard, Jacob ; Wang, Bing-Wu ; Coronado, Eugenio ; Gao, Song
刊名	CHEMICAL SCIENCE
	2015
关键词	SINGLE-ION MAGNETS CRYSTAL-FIELD PARAMETERS SIMPLE OVERLAP MODEL ANGULAR-RESOLVED MAGNETOMETRY ELECTROSTATIC MODEL COMPLEXES LIGAND DYSPROSIUM(III) LANTHANIDES BEHAVIOR
DOI	10.1039/c5sc01245g
英文摘要	A dysprosium based single-ion magnet is synthesized and characterized by the angular dependence of the single-crystal magnetic susceptibility. Ab initio and effective electrostatic analyses are performed using the molecular structures determined from single crystal X-ray diffraction at 20 K, 100 K and 300 K. Contrary to the common assumption, the results reveal that the structural thermal effects that may affect the energy level scheme and magnetic anisotropy below 100 K are negligible.; Natural Science Foundation of China [21290171, 21321001, 21302035, 21371043]; National Basic Research Program [2013CB933401]; EU (ERC Advanced Grant SPINMOL); Spanish MINECO [MAT2011-22785, MAT2014-56143-R, CTQ2014-52758-P]; Generalitat Valenciana (Prometeo Programme of Excellence); Generalitat Valenciana (ISIC Programme of Excellence); Alexander von Humboldt Stiftung; Danish National Research Foundation [DNRF93]; MINECO (Ramon y Cajal contract); Spanish MECD; SCI(E); EI; ARTICLE; jiang@lncmi.cnrs.fr; gaita@uv.es; coronado@uv.es; gaosong@pku.edu.cn; 8; 4587-4593; 6
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/421147]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Qian, Kang,Baldovi, Jose J.,Jiang, Shang-Da,et al. Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?[J]. CHEMICAL SCIENCE,2015.
APA	Qian, Kang.,Baldovi, Jose J..,Jiang, Shang-Da.,Gaita-Arino, Alejandro.,Zhang, Yi-Quan.,...&Gao, Song.(2015).Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?.CHEMICAL SCIENCE.
MLA	Qian, Kang,et al."Does the thermal evolution of molecular structures critically affect the magnetic anisotropy?".CHEMICAL SCIENCE (2015).