Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines | |
Ma, Wangyang ; Xu, Ling ; Zhang, Wen-Xiong ; Xi, Zhenfeng | |
刊名 | NEW JOURNAL OF CHEMISTRY |
2015 | |
关键词 | P-H BOND AMINE N-H COORDINATION CHEMISTRY SUBSTITUTED GUANIDINES C-H INSERTION REACTIONS HYDROPHOSPHINATION GUANYLATION ROUTE CYCLOPENTADIENYL |
DOI | 10.1039/c5nj01136a |
英文摘要 | The phosphaguanylation reaction of phosphines with carbodiimides catalyzed by half-sandwich yttrium tris(trimethylsilylmethyl) ate complexes is achieved for the first time to efficiently prepare phosphaguanidines. The catalyst system of the yttrium ate complex displays better catalytic activity than those of neutral yttrium complexes.; Natural Science Foundation of China; "973" program from National Basic Research Program of China [2012CB821600]; SCI(E); ARTICLE; wx_zhang@pku.edu.cn; 10; 7649-7655; 39 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/421027] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Ma, Wangyang,Xu, Ling,Zhang, Wen-Xiong,et al. Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines[J]. NEW JOURNAL OF CHEMISTRY,2015. |
APA | Ma, Wangyang,Xu, Ling,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2015).Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines.NEW JOURNAL OF CHEMISTRY. |
MLA | Ma, Wangyang,et al."Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines".NEW JOURNAL OF CHEMISTRY (2015). |
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