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Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines
Ma, Wangyang ; Xu, Ling ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名NEW JOURNAL OF CHEMISTRY
2015
关键词P-H BOND AMINE N-H COORDINATION CHEMISTRY SUBSTITUTED GUANIDINES C-H INSERTION REACTIONS HYDROPHOSPHINATION GUANYLATION ROUTE CYCLOPENTADIENYL
DOI10.1039/c5nj01136a
英文摘要The phosphaguanylation reaction of phosphines with carbodiimides catalyzed by half-sandwich yttrium tris(trimethylsilylmethyl) ate complexes is achieved for the first time to efficiently prepare phosphaguanidines. The catalyst system of the yttrium ate complex displays better catalytic activity than those of neutral yttrium complexes.; Natural Science Foundation of China; "973" program from National Basic Research Program of China [2012CB821600]; SCI(E); ARTICLE; wx_zhang@pku.edu.cn; 10; 7649-7655; 39
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/421027]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Ma, Wangyang,Xu, Ling,Zhang, Wen-Xiong,et al. Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines[J]. NEW JOURNAL OF CHEMISTRY,2015.
APA Ma, Wangyang,Xu, Ling,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2015).Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines.NEW JOURNAL OF CHEMISTRY.
MLA Ma, Wangyang,et al."Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines".NEW JOURNAL OF CHEMISTRY (2015).
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