Synthesis, Structural Characterization, and Reactivity of a   Fluorene-Based Calcium Oxycyclopentadienide Complex

doi:10.1021/acs.organomet.5b00059

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, Structural Characterization, and Reactivity of a Fluorene-Based Calcium Oxycyclopentadienide Complex
	Wei, Baosheng ; Li, Heng ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	ORGANOMETALLICS
	2015
关键词	ALKALINE-EARTH METALS HEAVY GRIGNARD-REAGENTS ORGANOMETALLIC CHEMISTRY CRYSTAL-STRUCTURES S-BLOCK BARIUM STRONTIUM METALLOCENES DERIVATIVES CATALYSIS
DOI	10.1021/acs.organomet.5b00059
英文摘要	Direct deprotonation of 9-fluorenol with Ca[N(SiMe3)(2)](2) efficiently generated a fluorene-based calcium oxycyclopentadienide complex, which is the first alkaline earth metal complex containing an oxycyclopentadienyl dianion ligand. The eta(5), eta(1), and eta(2) interactions between the oxycyclopentadienyl dianion ligand and the calcium center were observed in the solid state. The calcium oxycyclopentadienide complex displayed reductive character and multiple reactive sites. Its reactivity toward a range of electrophiles, especially acid chlorides, was investigated and discussed in detail. A wide variety of fluorene derivatives were synthesized.; 973 Program [2011CB808700]; Natural Science Foundation of China (NSFC); SCI(E); ARTICLE; wx_zhang@pku.edu.cn; zfxi@pku.edu.cn; 7; 1339-1344; 34
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/420477]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wei, Baosheng,Li, Heng,Zhang, Wen-Xiong,et al. Synthesis, Structural Characterization, and Reactivity of a Fluorene-Based Calcium Oxycyclopentadienide Complex[J]. ORGANOMETALLICS,2015.
APA	Wei, Baosheng,Li, Heng,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2015).Synthesis, Structural Characterization, and Reactivity of a Fluorene-Based Calcium Oxycyclopentadienide Complex.ORGANOMETALLICS.
MLA	Wei, Baosheng,et al."Synthesis, Structural Characterization, and Reactivity of a Fluorene-Based Calcium Oxycyclopentadienide Complex".ORGANOMETALLICS (2015).