Visible light promoted hydration of alkynes catalyzed by rhodium(III) porphyrins | |
Liu, Xu ; Liu, Lianghui ; Wang, Zikuan ; Fu, Xuefeng | |
刊名 | CHEMICAL COMMUNICATIONS |
2015 | |
关键词 | ANTI-MARKOVNIKOV HYDRATION TERMINAL ALKYNES RUTHENIUM COMPLEX GOLD(I) COMPLEXES WATER ACID ALCOHOLS METHANOL KETONES SYSTEM |
DOI | 10.1039/c5cc04015a |
英文摘要 | Visible light promoted hydration of a wide scope of alkynes to ketones catalyzed by rhodium(III) porphyrin complexes was described. The key intermediate beta-carbonyl alkyl was observed and independently synthesized. The rate of photolysis is over two orders of magnitude faster than that of the thermal process.; SCI(E); PubMed; ARTICLE; fuxf@pku.edu.cn; 59; 11896-11898; 51 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/419128] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Liu, Xu,Liu, Lianghui,Wang, Zikuan,et al. Visible light promoted hydration of alkynes catalyzed by rhodium(III) porphyrins[J]. CHEMICAL COMMUNICATIONS,2015. |
APA | Liu, Xu,Liu, Lianghui,Wang, Zikuan,&Fu, Xuefeng.(2015).Visible light promoted hydration of alkynes catalyzed by rhodium(III) porphyrins.CHEMICAL COMMUNICATIONS. |
MLA | Liu, Xu,et al."Visible light promoted hydration of alkynes catalyzed by rhodium(III) porphyrins".CHEMICAL COMMUNICATIONS (2015). |
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