A Novel Mechanochromic and Photochromic Polymer Film: When Rhodamine Joins Polyurethane | |
Wang, Zhijian ; Ma, Zhiyong ; Wang, Yao ; Xu, Zejun ; Luo, Yiyang ; Wei, Yen ; Jia, Xinru | |
刊名 | ADVANCED MATERIALS |
2015 | |
关键词 | MECHANICAL FORCE EMISSION MECHANOCHEMISTRY MECHANOPHORES COPOLYMERS MOLECULE SYSTEM PROBES COLOR CHAIN |
DOI | 10.1002/adma.201503424 |
英文摘要 | A rhodamine-based molecule, Rh-OH, is synthesized. Rh-OH exhibits a reversible mechanochromic luminescent character but a passivating response to UV light. An elastomeric polymer film based on polyurethane with embedded Rh-OH is prepared via a polycondensation reaction. The film shows mechanochromic and photochromic properties with reversible color change, which originates from the isomerization of the Rh-OH molecule from a twisted spirolactam in the ring-closed form to a planarized zwitterionic structure in the ring-open state.; National Natural Science Foundation of China [21174005]; National Basic Research Program of China [2011CB933300]; SCI(E); EI; PubMed; ARTICLE; xrjia@pku.edu.cn; 41; 6469-+; 27 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/417941] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wang, Zhijian,Ma, Zhiyong,Wang, Yao,et al. A Novel Mechanochromic and Photochromic Polymer Film: When Rhodamine Joins Polyurethane[J]. ADVANCED MATERIALS,2015. |
APA | Wang, Zhijian.,Ma, Zhiyong.,Wang, Yao.,Xu, Zejun.,Luo, Yiyang.,...&Jia, Xinru.(2015).A Novel Mechanochromic and Photochromic Polymer Film: When Rhodamine Joins Polyurethane.ADVANCED MATERIALS. |
MLA | Wang, Zhijian,et al."A Novel Mechanochromic and Photochromic Polymer Film: When Rhodamine Joins Polyurethane".ADVANCED MATERIALS (2015). |
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