Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode | |
Cheng, TR ; Huang, CH ; Gan, LB | |
刊名 | 材料化学杂志 |
1997 | |
关键词 | LANGMUIR-BLODGETT MULTILAYERS AMPHIPATHIC PORPHYRIN QUANTUM-WELL TUNNELING RATES TRANSIENT TRANSPORT BARRIER MOTION |
DOI | 10.1039/a606721b |
英文摘要 | An investigation of cathodic photocurrent response from a novel molecule with strong non-linear optical properties (second harmonic generation), (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide (MHPd)in LB films on transparent SnO2 glass has been-carried out. A quantum yield of 0.3% was obtained under irradiation with 450 nm light in 0.5 mol dm(-3) KCl electrolyte solution and ambient conditions. The studies of the relationship between the light intensity and the cathodic photocurrent indicate that MHPd assemblies perform a unimolecular process in charge recombination. The effects of bias voltage, oxygen and nitrogen; electron donors and accepters such as methyl viologen diiodide, ascorbic acid and hydroquinone were examined and have provided supporting evidence for the proposed electron-transfer mechanism.; Chemistry, Physical; Materials Science, Multidisciplinary; SCI(E); 24; ARTICLE; 4; 631-635; 7 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/402114] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Cheng, TR,Huang, CH,Gan, LB. Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode[J]. 材料化学杂志,1997. |
APA | Cheng, TR,Huang, CH,&Gan, LB.(1997).Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode.材料化学杂志. |
MLA | Cheng, TR,et al."Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode".材料化学杂志 (1997). |
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