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Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode
Cheng, TR ; Huang, CH ; Gan, LB
刊名材料化学杂志
1997
关键词LANGMUIR-BLODGETT MULTILAYERS AMPHIPATHIC PORPHYRIN QUANTUM-WELL TUNNELING RATES TRANSIENT TRANSPORT BARRIER MOTION
DOI10.1039/a606721b
英文摘要An investigation of cathodic photocurrent response from a novel molecule with strong non-linear optical properties (second harmonic generation), (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide (MHPd)in LB films on transparent SnO2 glass has been-carried out. A quantum yield of 0.3% was obtained under irradiation with 450 nm light in 0.5 mol dm(-3) KCl electrolyte solution and ambient conditions. The studies of the relationship between the light intensity and the cathodic photocurrent indicate that MHPd assemblies perform a unimolecular process in charge recombination. The effects of bias voltage, oxygen and nitrogen; electron donors and accepters such as methyl viologen diiodide, ascorbic acid and hydroquinone were examined and have provided supporting evidence for the proposed electron-transfer mechanism.; Chemistry, Physical; Materials Science, Multidisciplinary; SCI(E); 24; ARTICLE; 4; 631-635; 7
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/402114]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Cheng, TR,Huang, CH,Gan, LB. Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode[J]. 材料化学杂志,1997.
APA Cheng, TR,Huang, CH,&Gan, LB.(1997).Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode.材料化学杂志.
MLA Cheng, TR,et al."Investigation of the photoelectric conversion of a novel molecule (E)-N-methyl-4-{2-[4-(dihexadecylamino)phenyl]ethenyl}pyridazinium iodide, in LB films fabricated on an SnO2 electrode".材料化学杂志 (1997).
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