Applications of Typical Supramolecular Systems in the Field of   Radiochemistry

CORC > 北京大学 > 化学与分子工程学院

	Applications of Typical Supramolecular Systems in the Field of Radiochemistry
	Shen Xinghai ; Zhang Jingjing ; Gao Song ; Fu Suzhen ; Sun Taoxiang ; Fu Jing ; Zhang Hongjuan ; Chen Qingde ; Gao Hongcheng
刊名	化学进展
	2011
关键词	supramolecular chemistry radiochemistry separation of metal ions macrocyclic compounds ionic imprinting LEVEL LIQUID WASTE IMPREGNATED POLYMERIC COMPOSITE MICELLE-MEDIATED EXTRACTION TEMPERATURE IONIC LIQUIDS SOLID-PHASE EXTRACTION SUPERCRITICAL CARBON-DIOXIDE BIS(2-ETHYLHEXYL) PHOSPHATE COMPLEXES GRAFTED TH(IV)-IMPRINTED POLYMERS CATION-EXCHANGE RESIN STICKY SPHERES MODEL
英文摘要	Supramolecular chemistry is defined as "chemistry beyond the molecule", bearing on the organized entities of higher complexity that result from the association of two or more chemical species held together by intermolecular forces. Now, the applications of supramolecular chemistry in the realm of radiochemistry have attracted much attention. In this article, the separation of important metal ions by two kinds of supramolecular systems and ionic imprinted polymers (HP) is discussed, which demonstrates the significant roles of supramolecular systems in the field of radiochemistry. Meanwhile, the first type is supermolecules resulted from the intermolecular association of a host molecule and its substrates, where the host molecules are mainly macrocyclic compounds ( such as crown ethers, calixarene, calix crown ethers and so on). The second type is supramolecular assemblies induced by the spontaneous association of a large undefined number of components into a specific phase, including reversed micelles, microemulsions and liquid membranes. IIPs can recognize and separate metal ions selectively, which realizes the recognition function of supramolecular chemistry. The transport function of supramolecular chemistry is also well interpreted in the separation of metal ions by liquid membrane. Besides, the perspectives of supramolecular chemistry in the field of radiochemistry are also presented.; Chemistry, Multidisciplinary; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 0; ARTICLE; 7,SI; 1386-1399; 23
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/313147]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Shen Xinghai,Zhang Jingjing,Gao Song,et al. Applications of Typical Supramolecular Systems in the Field of Radiochemistry[J]. 化学进展,2011.
APA	Shen Xinghai.,Zhang Jingjing.,Gao Song.,Fu Suzhen.,Sun Taoxiang.,...&Gao Hongcheng.(2011).Applications of Typical Supramolecular Systems in the Field of Radiochemistry.化学进展.
MLA	Shen Xinghai,et al."Applications of Typical Supramolecular Systems in the Field of Radiochemistry".化学进展 (2011).