Synthesis and crystal structure of triethyl   1,2,2-triphenylpyrrolidine-3,4,5-tricarboxylate, a proline derivative

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	Synthesis and crystal structure of triethyl 1,2,2-triphenylpyrrolidine-3,4,5-tricarboxylate, a proline derivative
	Xu, JX ; Jiao, P ; Wang, ZM
刊名	结构化学
	1999
关键词	pyrrolidine synthesis crystal structure proline derivative
英文摘要	The title compound (C31H33NO6, M-r = 515.58) was synthesized by the reaction of N-diphenylmethylidene aniline and ethyl diazoacetate. Its crystal belongs to the orthorhombic system, space group Pbca, with a = 11.746(1), b = 17.179(1), c = 27.792(2) Angstrom, V = 5608.0(7) Angstrom(3), Z = 8, D-c = 1.221 g/cm(3), F(000) = 2192, mu = 0.084 mm(-1), lambda(MoK alpha) = 0.71073 Angstrom. Refinement with 343 parameters and 3071 independent reflections with I>2 sigma(I) gave R = 0.087 and wR = 0.22. In the title compound, the pyrrolidine ring system is in an envelope conformation with the atoms C (1), N(1), C(3) and C(4) in common plane and the atom C(2) lying 0.622(3) Angstrom out of this plane. The ethoxycarbonyl groups on the atoms C(1) and C(3) are in the same side of the pyrrolidine ring while the ethoxycarbonyl group on the atom C(2) and the phenyl group on the atom N(1) are in the other side.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000081538300016&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; Crystallography; SCI(E); 中文核心期刊要目总览(PKU); 中国科学引文数据库(CSCD); 0; ARTICLE; 4; 310-314; 18
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/312808]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xu, JX,Jiao, P,Wang, ZM. Synthesis and crystal structure of triethyl 1,2,2-triphenylpyrrolidine-3,4,5-tricarboxylate, a proline derivative[J]. 结构化学,1999.
APA	Xu, JX,Jiao, P,&Wang, ZM.(1999).Synthesis and crystal structure of triethyl 1,2,2-triphenylpyrrolidine-3,4,5-tricarboxylate, a proline derivative.结构化学.
MLA	Xu, JX,et al."Synthesis and crystal structure of triethyl 1,2,2-triphenylpyrrolidine-3,4,5-tricarboxylate, a proline derivative".结构化学 (1999).