A convenient synthesis of chiral dioxocyclens and application as chiral solvating agents | |
Yuan, Q ; Fu, EQ ; Wu, XJ ; Fang, MH ; Xue, P ; Wu, CT ; Chen, JH | |
刊名 | 四面体通讯 |
2002 | |
关键词 | RECOGNITION MACROCYCLES SEPARATION |
DOI | 10.1016/S0040-4039(02)00623-8 |
英文摘要 | This paper report. a very short and efficient synthesis of chiral dioxocyclens starting, from natural amino acids. NMR experiments undertaken to assess the chiral recognition properties of these chiral macrocycles. The NMR spectra of mandelic acid or its derivatives in the presence and absence of the chiral dioxocyclens showed that these macrocycles have different enantiomeric discriminating ability, It was revealed that this type of dioxocyclen may be promising hosts Cor chiral discrimination. (C) 2002 Elsevier Science Ltd. All rights reserved.; Chemistry, Organic; SCI(E); 0; ARTICLE; 21; 3935-3937; 43 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/258017] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Yuan, Q,Fu, EQ,Wu, XJ,et al. A convenient synthesis of chiral dioxocyclens and application as chiral solvating agents[J]. 四面体通讯,2002. |
APA | Yuan, Q.,Fu, EQ.,Wu, XJ.,Fang, MH.,Xue, P.,...&Chen, JH.(2002).A convenient synthesis of chiral dioxocyclens and application as chiral solvating agents.四面体通讯. |
MLA | Yuan, Q,et al."A convenient synthesis of chiral dioxocyclens and application as chiral solvating agents".四面体通讯 (2002). |
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