Manganese azides based on co-ligands with a flexible tail: Diverse   structural and magnetic properties

doi:10.1002/ejic.200500691

CORC > 北京大学 > 化学与分子工程学院

	Manganese azides based on co-ligands with a flexible tail: Diverse structural and magnetic properties
	Bai, SQ ; Gao, EQ ; He, Z ; Fang, CJ ; Yue, YF ; Yan, CH
刊名	欧洲无机化学杂志
	2006
关键词	azides coordination polymers ligand design magnetic properties manganese FERROMAGNETIC-ANTIFERROMAGNETIC INTERACTIONS TOPOLOGICAL FERRIMAGNETIC BEHAVIOR MONTE-CARLO-SIMULATION COORDINATION POLYMERS CRYSTAL-STRUCTURE MAGNETOSTRUCTURAL CORRELATIONS SPONTANEOUS RESOLUTION ALTERNATING SEQUENCE WEAK FERROMAGNETISM METAL-COMPLEXES
DOI	10.1002/ejic.200500691
英文摘要	Three azido-bridged coordination polymers, namely [Mn(L-1)(N-3)(2)](n) (1), [Mn(L-2) (N-3)(2)](n) (2), and [Mn(L-3) (N-3)(2)](n) (3) [L-1 = N-(2-pyridylmethylene)methylamine, L-2 = N-(2-pyridylmethylene)methylamine, and L-3 = N-(2-pyridylmethylene)octylamine], have been synthesized with Schiff-base co-ligands with flexible tails, and their structures and magnetic properties characterized. Complex 1 is composed of one-dimensional, uniform chains with double end-on (EO) azido bridges, complex 2 consists of (6,3) net, layers in which double EO azido-bridged dimers are interlinked by single end-to-end (EE) azido bridges, and complex 3 contains chains of Mn-II ions bridged by alternating double EO and double EE azido bridges. Magnetically, 1 is a metamagnet built of ferromagnetic chains, 2 exhibits weak ferromagnetism due to spin canting, and 3 shows alternate ferro- and antiferromagnetic intrachain interactions. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheirn, Germany, 2006).; Chemistry, Inorganic & Nuclear; SCI(E); 35; ARTICLE; 2; 407-415
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/252369]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Bai, SQ,Gao, EQ,He, Z,et al. Manganese azides based on co-ligands with a flexible tail: Diverse structural and magnetic properties[J]. 欧洲无机化学杂志,2006.
APA	Bai, SQ,Gao, EQ,He, Z,Fang, CJ,Yue, YF,&Yan, CH.(2006).Manganese azides based on co-ligands with a flexible tail: Diverse structural and magnetic properties.欧洲无机化学杂志.
MLA	Bai, SQ,et al."Manganese azides based on co-ligands with a flexible tail: Diverse structural and magnetic properties".欧洲无机化学杂志 (2006).