The crystal structure of hexaammonium diacetyl-octa-molybdate   tetrahydrate

doi:10.1002/crat.200510631

CORC > 北京大学 > 化学与分子工程学院

	The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate
	Xiao, ZC ; Wei, YG ; Xu, L ; Wang, Y
刊名	crystal research and technology
	2006
关键词	diacetyl-octamolybdate(VI) polyoxometalates crystal structure
DOI	10.1002/crat.200510631
英文摘要	The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate, (NH4)(42)[Mo132O372 (CH3COO)(30)(H2O)(72)] is documented. The crystals are triclinic, space group P-1, with a=8.1018(16) angstrom, b=10.334(2) angstrom, c=12.238(2) angstrom, alpha=68.20(3)degrees, beta=74.98(3)degrees, gamma=67.25(3)degrees, V=869.3(3) angstrom, Z=1. The structure. was solved by direct methods and refined by least squares methods to a Final R1 = 0.0374 and wR2 = 0. 1074 for 3805 observed reflections with I > 2 sigma(I). The structure contains ammonium cations and isolated acetyl octamolybdate(6-)anions, [Mo8O28(CH3CO)(2)](6-). The crystallographic data of the structure was deposited with the Cambridge Data Center as No. CCDC 249565. (c) 2006 WILEYNCH Verlag GmbH & Co. KGaA, Weinheim.; Crystallography; SCI(E); EI; 1; ARTICLE; 6; 595-599; 41
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/252077]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xiao, ZC,Wei, YG,Xu, L,et al. The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate[J]. crystal research and technology,2006.
APA	Xiao, ZC,Wei, YG,Xu, L,&Wang, Y.(2006).The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate.crystal research and technology.
MLA	Xiao, ZC,et al."The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate".crystal research and technology (2006).