Naphthyl amines as novel organoimido ligands for design of POM-based   organic-inorganic hybrids: Synthesis, structural characterization, and   supramolecular assembly of (Bu4N)(2)[Mo6O18N(Naph-1)]

doi:10.1021/cg0600694

CORC > 北京大学 > 化学与分子工程学院

	Naphthyl amines as novel organoimido ligands for design of POM-based organic-inorganic hybrids: Synthesis, structural characterization, and supramolecular assembly of (Bu4N)(2)[Mo6O18N(Naph-1)]
	Zhu, Y ; Xiao, ZC ; Ge, N ; Wang, N ; Wei, YG ; Wang, Y
刊名	crystal growth design
	2006
关键词	MAIN-CHAIN-POLYOXOMETALATE AROMATIC-AMINES DERIVATIVES HEXAMOLYBDATE FUNCTIONALIZATION < POLYMERS CLUSTERS CRYSTAL MO6O19> 2
DOI	10.1021/cg0600694
英文摘要	A novel naphthylimido derivative of hexamolybdate, (Bu4N)(2)[Mo6O18N(Naph-1)] ( 1), was synthesized for the first time by the reaction of octamolybdate ion and 1-naphthyl amine hydrochloride with DCC (N, N,-dicyclohexylcarbodiimide) as a dehydrating agent. The ultraviolet-visible absorption spectrum shows the lowest energy electronic transition of 1 occurs at 383 nm, which is dramatically red-shifted compared to that of [Mo6O19](2-) and other monosubstituted phenylimido hexamolybdates reported in the literature. Moreover, cyclic voltammetry studies on compound 1 show the reversible reduction wave at - 0.53 V, which is cathodically shifted relative to that of [Mo6O19](2-). Another interesting characteristic of 1 is that the cluster anions form supramolecular 1D chains via C- H center dot center dot center dot O hydrogen bonding interactions.; Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary; SCI(E); 22; ARTICLE; 7; 1620-1625; 6
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/251897]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhu, Y,Xiao, ZC,Ge, N,et al. Naphthyl amines as novel organoimido ligands for design of POM-based organic-inorganic hybrids: Synthesis, structural characterization, and supramolecular assembly of (Bu4N)(2)[Mo6O18N(Naph-1)][J]. crystal growth design,2006.
APA	Zhu, Y,Xiao, ZC,Ge, N,Wang, N,Wei, YG,&Wang, Y.(2006).Naphthyl amines as novel organoimido ligands for design of POM-based organic-inorganic hybrids: Synthesis, structural characterization, and supramolecular assembly of (Bu4N)(2)[Mo6O18N(Naph-1)].crystal growth design.
MLA	Zhu, Y,et al."Naphthyl amines as novel organoimido ligands for design of POM-based organic-inorganic hybrids: Synthesis, structural characterization, and supramolecular assembly of (Bu4N)(2)[Mo6O18N(Naph-1)]".crystal growth design (2006).