Effect of borane source on the enantioselectivity in the enantiopure   oxazaborolidine-catalyzed asymmetric borane reduction of ketones

doi:10.1002/hc.20370

CORC > 北京大学 > 化学与分子工程学院

	Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones
	Wang, Xiao ; Du, Juanjuan ; Liu, Han ; Du, Da-Ming ; Xu, Jiaxi
刊名	heteroatom chemistry
	2007
关键词	HIGH ENANTIOMERIC EXCESS PROCHIRAL KETONES CHIRAL OXAZABOROLIDINE CARBONYL-COMPOUNDS AROMATIC KETONES EFFICIENT SYNTHESIS SECONDARY ALCOHOLS PRACTICAL METHOD AMINO-ALCOHOLS REDUCING AGENT
DOI	10.1002/hc.20370
英文摘要	The effect of borane source on enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones has been investigated by using (S)-3,1,2-oxazaborobicyclo[3.3.0]octane and (S)-7,3,1,2-thiaxazaborobicyclo[3.3.0]octane as catalysts. The results indicate that the enantioselective order of different borane sources is borane-dimethyl sulfide < borane-N,N-diethylaniline < borane-THF for the asymmetric reduction of a ketone under the same conditions. (c) 2007 Wiley Periodicals, Inc.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000251367100005&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); 6; ARTICLE; 7; 740-746; 18
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/250856]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Xiao,Du, Juanjuan,Liu, Han,et al. Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones[J]. heteroatom chemistry,2007.
APA	Wang, Xiao,Du, Juanjuan,Liu, Han,Du, Da-Ming,&Xu, Jiaxi.(2007).Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones.heteroatom chemistry.
MLA	Wang, Xiao,et al."Effect of borane source on the enantioselectivity in the enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones".heteroatom chemistry (2007).