Investigation on photophysical properties of a substituted 3H-indole-modified beta-cyclodextrin II. Efficient photoinduced energy transfer with naphthalene and its derivatives | |
Wu, Aihua ; Shen, Xinghai ; Gao, Hongcheng | |
刊名 | journal of photochemistry and photobiology a chemistry
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2007 | |
关键词 | supramolecular assemblies energy transfer time-resolved fluorescence MODIFIED ALPHA-CYCLODEXTRIN ELECTRON-TRANSFER MULTICHROMOPHORIC CYCLODEXTRINS AROMATIC-HYDROCARBONS AQUEOUS-SOLUTIONS FLUORESCENCE INCLUSION EXCITATION COMPLEXES MICELLES |
DOI | 10.1016/j.jphotochem.2006.05.023 |
英文摘要 | Photoinduced energy transfer is observed in the supramolecular assemblies of mono-6-deoxy-(2-[(p-amino) phenyl]-3,3-dimethyl-5-carboxyl-3H-indole)-beta-CD (compound A) with naphthalene and its derivatives, which are stabilized via hydrophobic interactions in aqueous solutions. According to Foster theory, the critical transfer radius R(0) was calculated. It was found that the energy transfer efficiency from naphthalene and its derivatives to compound A is very high and is increased with increasing their inclusion percents in the beta-CD cavity of compound A. Energy transfer efficiencies for 2-methoxynaphthalene and 2-naphthol are not much different, but larger than that of naphthalene at the same molar ratio of donor to acceptor. But, when the molar ratio reaching 1: 10, the difference in the energy transfer efficiency for the three donors is negligible. (c) 2006 Published by Elsevier B.V.; Chemistry, Physical; SCI(E); 4; ARTICLE; 2-3; 144-149; 185 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/250380] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wu, Aihua,Shen, Xinghai,Gao, Hongcheng. Investigation on photophysical properties of a substituted 3H-indole-modified beta-cyclodextrin II. Efficient photoinduced energy transfer with naphthalene and its derivatives[J]. journal of photochemistry and photobiology a chemistry,2007. |
APA | Wu, Aihua,Shen, Xinghai,&Gao, Hongcheng.(2007).Investigation on photophysical properties of a substituted 3H-indole-modified beta-cyclodextrin II. Efficient photoinduced energy transfer with naphthalene and its derivatives.journal of photochemistry and photobiology a chemistry. |
MLA | Wu, Aihua,et al."Investigation on photophysical properties of a substituted 3H-indole-modified beta-cyclodextrin II. Efficient photoinduced energy transfer with naphthalene and its derivatives".journal of photochemistry and photobiology a chemistry (2007). |
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