Spin-canting in a 1D chain Mn(II) complex with alternating double end-on   and double end-to-end azido bridging ligands

doi:10.1016/j.inoche.2007.04.004

CORC > 北京大学 > 化学与分子工程学院

	Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands
	Zhang, Jian-Ying ; Liu, Cai-Ming ; Zhang, De-Qing ; Gao, Song ; Zhu, Dao-Ben
刊名	inorganic chemistry communications
	2007
关键词	manganese(II) complex azido ligand coordination polymer spin canting magnetic property crystal structure FERROMAGNETIC-ANTIFERROMAGNETIC INTERACTIONS MANGANESE(II) COORDINATION POLYMERS MONTE-CARLO-SIMULATION MAGNETIC-PROPERTIES CRYSTAL-STRUCTURE STRUCTURAL-CHARACTERIZATION WEAK FERROMAGNETISM MAGNETOSTRUCTURAL CORRELATIONS SPONTANEOUS RESOLUTION MOLECULAR MATERIAL
DOI	10.1016/j.inoche.2007.04.004
英文摘要	A new one-dimensional (II)) azido-bridged manganese(II) complex, [Mn(dpq)(N-3)2](n) [dpq = dipyrido-(3,2-d:2',3'-f)-quinoxaline] (1), was synthesized and characterized. Crystal structure study reveals that 1 contains a ID manganese(II) chain bridged by alternating double end-to-end (EE) and double end-on (EO) azido ligands. The strong interchain pi-pi stacking interaction extends the structure into a 2D supramolecular array. The analysis of magnetic data indicates that the EO- and EE-azido bridges mediate the ferromagnetic and antiferromagnetic interactions, respectively. Interestingly, complex 1 exhibits a weak ferromagnetic property below 6 K probably due to spin canting. (c) 2007 Elsevier B.V. All rights reserved.; Chemistry, Inorganic & Nuclear; SCI(E); 0; ARTICLE; 8; 897-901; 10
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/249945]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,et al. Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands[J]. inorganic chemistry communications,2007.
APA	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,Gao, Song,&Zhu, Dao-Ben.(2007).Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands.inorganic chemistry communications.
MLA	Zhang, Jian-Ying,et al."Spin-canting in a 1D chain Mn(II) complex with alternating double end-on and double end-to-end azido bridging ligands".inorganic chemistry communications (2007).