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Tunable One-Dimensional Helical Nanostructures: From Supramolecular Self-Assemblies to Silica Nanomaterials
Lin, Yiyang ; Qiao, Yan ; Gao, Chen ; Tang, Peifeng ; Liu, Yu ; Li, Zhibo ; Yan, Yun ; Huang, Jianbin
刊名chemistry of materials
2010
关键词SOL-GEL TRANSCRIPTION ROD-COIL AMPHIPHILES MESOPOROUS SILICA ORGANOGEL FIBERS LIPID TUBULES NANOTUBES CHIRALITY NANOHELICES SURFACTANT CREATION
DOI10.1021/cm102181e
英文摘要Herein, one-dimensional double helix is fabricated via supramolecular self-assembly of a sugar-based amphiphile, which can be utilized as soft template to synthesize silica double helices and nanotubes through sol-gel reaction of tetraethyl orthosilicate (TEOS). The self-assembled double helix can be rationally transformed into nonhelical fibers with the aid of conventional ionic surfactants. It is suggested that the introduction of ionic surfactant will impart electrostatic repulsion inside double helix and shape double helices into nanofibers. Interestingly the nonhelical fibers coassembled by C(4)AG and cationic surfactants have been proven to direct the preparation of single-stranded helical SiO(2) through sol-gel polycondensation. This is the first time that both double and single-stranded silica helix have been created in one system.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000285429000023&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; Materials Science, Multidisciplinary; SCI(E); 36; ARTICLE; 24; 6711-6717; 22
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/241307]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Lin, Yiyang,Qiao, Yan,Gao, Chen,et al. Tunable One-Dimensional Helical Nanostructures: From Supramolecular Self-Assemblies to Silica Nanomaterials[J]. chemistry of materials,2010.
APA Lin, Yiyang.,Qiao, Yan.,Gao, Chen.,Tang, Peifeng.,Liu, Yu.,...&Huang, Jianbin.(2010).Tunable One-Dimensional Helical Nanostructures: From Supramolecular Self-Assemblies to Silica Nanomaterials.chemistry of materials.
MLA Lin, Yiyang,et al."Tunable One-Dimensional Helical Nanostructures: From Supramolecular Self-Assemblies to Silica Nanomaterials".chemistry of materials (2010).
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