Supramolecular Self-Assembly of 1D and 3D Heterometallic Coordination   Polymers with Triruthenium Building Blocks

doi:10.1002/chem.201202084

CORC > 北京大学 > 化学与分子工程学院

	Supramolecular Self-Assembly of 1D and 3D Heterometallic Coordination Polymers with Triruthenium Building Blocks
	Chan, Sharon Lai-Fung ; Gao, Song ; Chui, Stephen Sin-Yin ; Shek, Lam ; Huang, Jie-Sheng ; Che, Chi-Ming
刊名	chemistry a european journal
	2012
关键词	coordination polymers hydrothermal synthesis metal-metal interactions ruthenium self-assembly EFFECTIVE CORE POTENTIALS METAL-ORGANIC FRAMEWORKS ONE-DIMENSIONAL POLYMERS MULTIPLE BONDS MOLECULAR CALCULATIONS ELECTRONIC-STRUCTURE CRYSTAL-STRUCTURE ACTIVE-SITE COMPLEXES TRINUCLEAR
DOI	10.1002/chem.201202084
英文摘要	Ru-3(TSA)(6) (1; H(2)TSA=2-thiosalicylic acid), which bears six peripheral carboxylate groups and was isolated in the form [NEt4](1.5)[Ru-3(HTSA)(2)(TSA)(4)](OAc)(0.5)center dot 3.5H(2)O, serves as a building block for assembly of heterometallic coordination polymers. Treatment of 1 with [Fe(acac)(3)] (acac=acetylacetonate) in EG/H2O (EG=ethylene glycol) afforded 1D Ru-3-Fe coordination polymer 2 by means of the connection of the building block 1 through iron centers. Treatment of 1 with MnCl2 in EG resulted in the formation of 1D Ru-3-Mn-3 coordination polymer 3, which features self-assembled polynuclear linking units Mn-3(OCH2CH2O)(3), each of which contains a planar Mn3O3 ring. By treating 1 with Gd(NO3)(3) and NaHCO3 in EG, a 3D Ru-3-Gd-6 coordination polymer 4 was obtained; this 3D coordination polymer features unprecedented Gd-6-(mu(3)-CO3)(4) units. The magnetic properties of 1-4, along with DFT calculations on the electronic structure of 1, are also described.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000308310100013&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); EI; 4; ARTICLE; 36; 11228-11237; 18
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/231740]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chan, Sharon Lai-Fung,Gao, Song,Chui, Stephen Sin-Yin,et al. Supramolecular Self-Assembly of 1D and 3D Heterometallic Coordination Polymers with Triruthenium Building Blocks[J]. chemistry a european journal,2012.
APA	Chan, Sharon Lai-Fung,Gao, Song,Chui, Stephen Sin-Yin,Shek, Lam,Huang, Jie-Sheng,&Che, Chi-Ming.(2012).Supramolecular Self-Assembly of 1D and 3D Heterometallic Coordination Polymers with Triruthenium Building Blocks.chemistry a european journal.
MLA	Chan, Sharon Lai-Fung,et al."Supramolecular Self-Assembly of 1D and 3D Heterometallic Coordination Polymers with Triruthenium Building Blocks".chemistry a european journal (2012).