TiO2 mesocrystals: Synthesis, formation mechanisms and applications | |
Cai JinGuang ; Qi LiMin | |
刊名 | science china chemistry
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2012 | |
关键词 | mesocrystals TiO2 formation mechanisms topotactic transformation oriented attachment mesoscale assembly UNIFORM NH4TIOF3 MESOCRYSTALS ANATASE TIO2 RUTILE TIO2 ORIENTED ATTACHMENT NANOSTRUCTURES CRYSTALLIZATION SUPERSTRUCTURES NANOCRYSTALS CONVERSION ARRAYS |
DOI | 10.1007/s11426-012-4706-7 |
英文摘要 | Mesocrystals, which are assemblies of crystallographically oriented nanocrystals, have received increasing attention due to their unique properties such as high crystallinity, high porosity, oriented subunit alignment, and similarity to highly sophisticated biominerals. However, the controlled synthesis of TiO2 mesocrystals has not been realized until recently, probably because of the difficulty in accurately controlling the reaction processes that produce TiO2 crystals. In this review, recent advances in the synthesis and applications of TiO2 mesocrystals are summarized with particular attention paid to the mechanisms of their formation. Three typical pathways for the preparation of TiO2 mesocrystals are discussed, namely topotactic transformation, direct synthesis in solution, and growth on supports. The potential applications of TiO2 mesocrystals in lithium ion batteries, photocatalysis, enzyme immobilization, and antireflection materials are also described.; Chemistry, Multidisciplinary; SCI(E); EI; 7; REVIEW; 11; 2318-2326; 55 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/230521] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Cai JinGuang,Qi LiMin. TiO2 mesocrystals: Synthesis, formation mechanisms and applications[J]. science china chemistry,2012. |
APA | Cai JinGuang,&Qi LiMin.(2012).TiO2 mesocrystals: Synthesis, formation mechanisms and applications.science china chemistry. |
MLA | Cai JinGuang,et al."TiO2 mesocrystals: Synthesis, formation mechanisms and applications".science china chemistry (2012). |
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