Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with   Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the   Silacyclobutene Ring

doi:10.1021/om401065c

CORC > 北京大学 > 化学与分子工程学院

	Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring
	Zhao, Jing ; Zhang, Shaoguang ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	organometallics
	2014
关键词	ORGANOMETALLIC CHEMISTRY GROUP-4 METALLOCENES ORGANIC-SYNTHESIS ALKYNE COMPLEXES TETHERED DIYNES ONE MOLECULE ZIRCONOCENE DERIVATIVES ZIRCONACYCLES ZIRCONIUM
DOI	10.1021/om401065c
英文摘要	The reaction of titanacyclobutene-silacyclobutene fused-ring complexes with nitriles was investigated. Formal insertion of the C-N triple bond of nitriles into the silacyclobutene ring was observed, affording their corresponding titanacyclobutene and six-membered azasilacycle fused-ring complexes. This reaction pattern with nitriles is totally different from that of their analogous zirconacyclobutene-silacyclobutene fused-ring complexes. The size effect of the central metals (Ti vs Zr) is considered as the major reason for the different reaction patterns.; Chemistry, Inorganic & Nuclear; Chemistry, Organic; SCI(E); EI; 3; ARTICLE; wx_zhang@pku.edu.cn; zfxi@pku.edu.cn; 1; 8-11; 33
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/216474]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring[J]. organometallics,2014.
APA	Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring.organometallics.
MLA	Zhao, Jing,et al."Reaction of Titanacyclobutene-Silacyclobutene Fused-Ring Complexes with Nitriles via Formal Insertion of the C-N Triple Bond of Nitrile into the Silacyclobutene Ring".organometallics (2014).