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	Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes
	Zhao, Jing ; Zhang, Shaoguang ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	coordination chemistry reviews
	2014
关键词	Zirconacycle Silacycle Metallacyclobutene Zirconacyclobutene-silacyclobutene fused complex Coordination Skeletal rearrangement C-C BOND GROUP-4 METALLOCENE COMPLEXES METAL-PROMOTED CYCLIZATION LATE TRANSITION-METALS TUNGSTEN TRIPLE BONDS 2 DIFFERENT ALKYNES SI-TETHERED DIYNES ZIRCONOCENE COMPLEXES CARBON BOND 5-MEMBERED ZIRCONACYCLOALLENOIDS
DOI	10.1016/j.ccr.2013.08.032
英文摘要	Coordination-induced skeletal rearrangement of transition-metal complexes is of fundamental interest both synthetically and mechanistically. Besides commonly observed ligand substitution, the coordination of ligands may greatly alter the steric and electronic environment around the metal center, thus activating the whole compound, resulting in novel rearrangement or cleavage of chemical bonds. Subsequent formations of chemical bonds would lead to synthetically useful methods for new transition-metal complexes and organic compounds. Zirconacycles have been proved to be very useful for synthetic organic and organometallic chemistry. The present review concentrates on the coordination-induced skeletal rearrangement of zirconacyclobutene-silacyclobutene fused complexes. When treated with nitriles, alkynes, ketones, or other unsaturated organic molecules, the zirconacyclobutene-silacyclobutene fused complexes underwent the coordination-induced rearrangement and new chemical bond forming process, other than the expected direct insertion reactions. Different types of rearrangements were observed depending on the coordinating unsaturated organic molecules. A variety of zirconacycles and organic products were formed efficiently from the zirconacyclobutene-silacyclobutene fused complexes and the unsaturated organic molecules through the coordination-induced rearrangement and new chemical bond forming process. (C) 2013 Elsevier B.V. All rights reserved.; Chemistry, Inorganic & Nuclear; SCI(E); 7; REVIEW; zfxi@pku.edu.cn; ,SI; 2-13; 270
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/211290]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes[J]. coordination chemistry reviews,2014.
APA	Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes.coordination chemistry reviews.
MLA	Zhao, Jing,et al."Coordination-induced skeletal rearrangements of zirconacyclobutene-silacyclobutene fused complexes".coordination chemistry reviews (2014).

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