Highly Regioselective Syntheses of Substituted Triphenylenes from   1,2,4-Trisubstituted Arenes via a Co-Catalyzed Intermolecular Alkyne   Cyclotrimerization

doi:10.1021/jo400570b

CORC > 北京大学 > 化学与分子工程学院

	Highly Regioselective Syntheses of Substituted Triphenylenes from 1,2,4-Trisubstituted Arenes via a Co-Catalyzed Intermolecular Alkyne Cyclotrimerization
	Xu, Lingmin ; Yu, Ruocheng ; Wang, Yuefan ; Chen, Jiahua ; Yang, Zhen
刊名	journal of organic chemistry
	2013
关键词	BENZENE-DERIVATIVES SUPERCRITICAL WATER 2+2+2 CYCLOADDITION TERMINAL ALKYNES SCHOLL REACTION DIELS-ALDER COBALT LIGAND CONSTRUCTION ACETYLENES
DOI	10.1021/jo400570b
英文摘要	Herein, we report the development of a new method for the syntheses of substituted triphenylenes from the corresponding 1,2,4-trisubstituted arenes, which were themselves generated in a highly regioselective manner according to an intermolecular alkyne cyclotrimerization reaction that was catalyzed by a novel Co-TMTU complex. This highly regioselective reaction for the formation of 1,2,4-trisubstituted arenes will be a valuable addition to the plethora of tools already available to synthetic chemists and encourage further mechanistic studies of this important alkyne trimerization process.; Chemistry, Organic; SCI(E); EI; PubMed; 11; ARTICLE; 11; 5744-5750; 78
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/190515]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xu, Lingmin,Yu, Ruocheng,Wang, Yuefan,et al. Highly Regioselective Syntheses of Substituted Triphenylenes from 1,2,4-Trisubstituted Arenes via a Co-Catalyzed Intermolecular Alkyne Cyclotrimerization[J]. journal of organic chemistry,2013.
APA	Xu, Lingmin,Yu, Ruocheng,Wang, Yuefan,Chen, Jiahua,&Yang, Zhen.(2013).Highly Regioselective Syntheses of Substituted Triphenylenes from 1,2,4-Trisubstituted Arenes via a Co-Catalyzed Intermolecular Alkyne Cyclotrimerization.journal of organic chemistry.
MLA	Xu, Lingmin,et al."Highly Regioselective Syntheses of Substituted Triphenylenes from 1,2,4-Trisubstituted Arenes via a Co-Catalyzed Intermolecular Alkyne Cyclotrimerization".journal of organic chemistry (2013).