Atom transfer radical polymerization of vinyl monomers in the presence of tetraethylthiuram disulfide | |
Qiu, KY ; Li, P ; Chen, XP | |
2003 | |
关键词 | atom transfer radical polymerization (ATRP) initiators REVERSE ATRP PROCESS INITIATING SYSTEM METHYL-METHACRYLATE ARENESULFONYL CHLORIDES STYRENE INIFERTER DCDPS/FECL3/PPH3 MMA |
英文摘要 | In situ ATRPs of MMA, St in the presence of TD catalyzed by kFeCl(3)/PPh3 and CuBr2/bpy have been studied, respectively. The results showed that the initiator Et2NCS2X (X = Cl or Br) and catalyst FeCl2 or CuBr were formed in situ from the initiating components and the polymerization exhibited living radical polymerization characteristics. In the case of St polymerization with TD/CuBr/bpy initiating system, an inverse ATRP was observed.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000184474400006&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Polymer Science; SCI(E); EI; CPCI-S(ISTP); 3 |
语种 | 英语 |
DOI标识 | 10.1002/masy.200390142 |
内容类型 | 其他 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/151630] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Qiu, KY,Li, P,Chen, XP. Atom transfer radical polymerization of vinyl monomers in the presence of tetraethylthiuram disulfide. 2003-01-01. |
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