Design of auxetic polymer self-assemblies | |
Wei, GY | |
2005 | |
关键词 | NEGATIVE POISSON RATIO MOLECULAR DESIGN NETWORKS SYSTEM |
英文摘要 | Alternating copolymers having a double-arrow-like "hard" block and a spring-like "soft" segment have been designed which can in principle self-assembly into two-dimensional supramolecular networks. Molecular-mechanics calculations show that such self-assemblies can be auxetic when the lengths of the block and the segment are carefully chosen, with one metastable supermolecule having one of its six Poisson ratios as negatively large as -11.86. The underlying principle of designing such auxetic self-assembly of copolymers with specified architecture is also given as are the deciding factors such as the packing geometry and the associated lattice energy in achieving the auxeticity. (c) 2005 WILEY-VCH Verlag GmbH A Co. KGaA, Weinheim.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000228020100032&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Physics, Condensed Matter; SCI(E); CPCI-S(ISTP); 25 |
语种 | 英语 |
DOI标识 | 10.1002/pssb.200460391 |
内容类型 | 其他 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/151601] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wei, GY. Design of auxetic polymer self-assemblies. 2005-01-01. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论