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Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak
Li, Xiaopei ; Fan, Xiaokun ; Huang, Kun ; Liu, Huizhou ; Zhao, Ying ; Wei, Yongju ; Liu, Cuige ; Xu, Yizhuang ; Noda, Isao ; Wu, Jinguang
刊名分子结构杂志
2014
关键词Two-dimensional asynchronous spectroscopy Intermolecular interaction Asynchronous 2-DIMENSIONAL CORRELATION SPECTROSCOPY SAMPLE DESIGN SCHEME INFRARED CORRELATION IONIC-LIQUID METAL-IONS BEHAVIOR COORDINATION COMPLEXES MECHANISM CONJUNCTION
DOI10.1016/j.molstruc.2014.01.046
英文摘要We explore whether it is possible to use 2D correlation spectrum to characterize intermolecular interactions between two solutes dissolved in the same solution when one substance does not possesses any characteristic peak. We demonstrate that the interaction can be manifested by characteristic cross peaks in 2D asynchronous correlated spectrum. The above cross peaks reflect the subtle spectral variations on the characteristic peak of another solute under intermolecular interaction. On the other hand, 2D synchronous spectrum is not suitable to characterize intermolecular interaction since the cross peaks contain irremovable interfering parts. The terbium-chloride/benzamide/methanol system is used to demonstrate that this approach is applicable in the real chemical system. (C) 2014 Elsevier B.V. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000337989900015&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; SCI(E); EI; 9; ARTICLE; khuang@home.ipe.ac.cn; xyz@pku.edu.cn; ,SI; 127-132; 1069
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/150444]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Li, Xiaopei,Fan, Xiaokun,Huang, Kun,et al. Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak[J]. 分子结构杂志,2014.
APA Li, Xiaopei.,Fan, Xiaokun.,Huang, Kun.,Liu, Huizhou.,Zhao, Ying.,...&Wu, Jinguang.(2014).Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak.分子结构杂志.
MLA Li, Xiaopei,et al."Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak".分子结构杂志 (2014).
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