Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak | |
Li, Xiaopei ; Fan, Xiaokun ; Huang, Kun ; Liu, Huizhou ; Zhao, Ying ; Wei, Yongju ; Liu, Cuige ; Xu, Yizhuang ; Noda, Isao ; Wu, Jinguang | |
刊名 | 分子结构杂志 |
2014 | |
关键词 | Two-dimensional asynchronous spectroscopy Intermolecular interaction Asynchronous 2-DIMENSIONAL CORRELATION SPECTROSCOPY SAMPLE DESIGN SCHEME INFRARED CORRELATION IONIC-LIQUID METAL-IONS BEHAVIOR COORDINATION COMPLEXES MECHANISM CONJUNCTION |
DOI | 10.1016/j.molstruc.2014.01.046 |
英文摘要 | We explore whether it is possible to use 2D correlation spectrum to characterize intermolecular interactions between two solutes dissolved in the same solution when one substance does not possesses any characteristic peak. We demonstrate that the interaction can be manifested by characteristic cross peaks in 2D asynchronous correlated spectrum. The above cross peaks reflect the subtle spectral variations on the characteristic peak of another solute under intermolecular interaction. On the other hand, 2D synchronous spectrum is not suitable to characterize intermolecular interaction since the cross peaks contain irremovable interfering parts. The terbium-chloride/benzamide/methanol system is used to demonstrate that this approach is applicable in the real chemical system. (C) 2014 Elsevier B.V. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000337989900015&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; SCI(E); EI; 9; ARTICLE; khuang@home.ipe.ac.cn; xyz@pku.edu.cn; ,SI; 127-132; 1069 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/150444] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li, Xiaopei,Fan, Xiaokun,Huang, Kun,et al. Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak[J]. 分子结构杂志,2014. |
APA | Li, Xiaopei.,Fan, Xiaokun.,Huang, Kun.,Liu, Huizhou.,Zhao, Ying.,...&Wu, Jinguang.(2014).Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak.分子结构杂志. |
MLA | Li, Xiaopei,et al."Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak".分子结构杂志 (2014). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论