Synthesis, crystal structure, and application of an acenaphtho[1,2-k]   fluoranthene diimide derivative

doi:10.1007/s11426-014-5282-9

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, crystal structure, and application of an acenaphtho[1,2-k] fluoranthene diimide derivative
	Ding, Lin ; Yang, Chiyuan ; Su, Zhongmin ; Pei, Jian
刊名	science china chemistry
	2015
关键词	acenaphtho fluoranthene diimide lithium-halogen exchange Diels-Alder reaction electron acceptor solar cell FIELD-EFFECT TRANSISTORS THIN-FILM TRANSISTORS POLYMER SOLAR-CELLS ELECTRON-ACCEPTOR PERFORMANCE TRANSPORT DESIGN
DOI	10.1007/s11426-014-5282-9
英文摘要	Organic electron acceptor materials play an important role in organic electronics. Recently, many organic electron acceptors have been developed, in which aromatic fused-imides have proved to be a promising family of excellent electron acceptors. We report the first synthesis of a novel aromatic fused-imide, acenaphtho[1, 2-k]fluoranthene diimide derivative (AFI), using lithium-halogen exchange and Diels-Alder reactions. The construction of a large conjugated plane and the introduction of electron-withdrawing imide groups endow AFI with a low lowest unoccupied molecular orbital (LUMO) level of -3.80 eV. AFI exhibits a regular molecular arrangement and strong pi-pi interactions in the single-crystal structure, which indicates its potential application in organic electronic devices. Solar cell devices that were fabricated using AFI as the electron acceptor and P3HT as the electron donor achieved an energy conversion efficiency of 0.33%.; Chemistry, Multidisciplinary; SCI(E); EI; 中国科学引文数据库(CSCD); 0; ARTICLE; zmsu@nenu.edu.cn; jianpei@pku.edu.cn; 2,SI; 364-369; 58
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150310]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Ding, Lin,Yang, Chiyuan,Su, Zhongmin,et al. Synthesis, crystal structure, and application of an acenaphtho[1,2-k] fluoranthene diimide derivative[J]. science china chemistry,2015.
APA	Ding, Lin,Yang, Chiyuan,Su, Zhongmin,&Pei, Jian.(2015).Synthesis, crystal structure, and application of an acenaphtho[1,2-k] fluoranthene diimide derivative.science china chemistry.
MLA	Ding, Lin,et al."Synthesis, crystal structure, and application of an acenaphtho[1,2-k] fluoranthene diimide derivative".science china chemistry (2015).