Microporous Aluminoborates with Large Channels: Structural and Catalytic   Properties

doi:10.1002/anie.201106310

CORC > 北京大学 > 化学与分子工程学院

	Microporous Aluminoborates with Large Channels: Structural and Catalytic Properties
	Yang, Tao ; Bartoszewicz, Agnieszka ; Ju, Jing ; Sun, Junliang ; Liu, Zheng ; Zou, Xiaodong ; Wang, Yingxia ; Li, Guobao ; Liao, Fuhui ; Martin-Matute, Belen ; Lin, Jianhua
刊名	angewandte chemie international edition
	2011
关键词	aluminoborates borates cyanosilylation heterogeneous catalysis microporous materials HIGH OPTICAL PURITY MOLECULAR-SIEVES ACID CATALYSIS ZEOLITES CYANOHYDRINS FRAMEWORK SITES
DOI	10.1002/anie.201106310
英文摘要	Channel zapping: PKU-1 and newly synthesized PKU-2 (Al(2)B(5)O(9)(OH)(3)?n?H(2)O; see picture) possess microporous structures with 18-ring and 24-ring channels, respectively. They show high reactivity and size selectivity in the cyanosilylation of aldehydes as heterogeneous Lewis acid catalysts. The different channel sizes determine the substrate selectivity. These examples demonstrate the potential of octahedron-based aluminoborate channels in catalysis.Copyright ? 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 26; ARTICLE; 52; 12555-12558; 50
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/149940]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Tao,Bartoszewicz, Agnieszka,Ju, Jing,et al. Microporous Aluminoborates with Large Channels: Structural and Catalytic Properties[J]. angewandte chemie international edition,2011.
APA	Yang, Tao.,Bartoszewicz, Agnieszka.,Ju, Jing.,Sun, Junliang.,Liu, Zheng.,...&Lin, Jianhua.(2011).Microporous Aluminoborates with Large Channels: Structural and Catalytic Properties.angewandte chemie international edition.
MLA	Yang, Tao,et al."Microporous Aluminoborates with Large Channels: Structural and Catalytic Properties".angewandte chemie international edition (2011).