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A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry
Chen, Lisha ; Chang, Fengxia ; Meng, Lingchen ; Li, Meixian ; Zhu, Zhiwei
刊名analyst
2014
关键词L-DOPA MASS-SPECTROMETRY AMINO
DOI10.1039/c4an00098f
英文摘要We demonstrate, for the first time, an electrochemical sensor that provides antipodal signals upon application of square wave voltammetry (SWV), for enantioselective recognition of 3,4-dihydroxyphenylalanine based on chiral single-walled carbon nanotubes (SWCNTs) in the presence of sulphuric acid. Interestingly, the enantioselectivity was not observed using the common method of cyclic voltammetry (CV) but the SWV peak currents of enantiomers were found to be quite different and hence the enantiomers could be successfully recognized. Moreover, the antipodal signals provided by two SWV scan modes offer the possibility for results to be confirmed mutually, showing a great practical value and analytical application prospects.; Chemistry, Analytical; SCI(E); PubMed; 4; ARTICLE; zwzhu@pku.edu.cn; 9; 2243-2248; 139
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/149713]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Chen, Lisha,Chang, Fengxia,Meng, Lingchen,et al. A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry[J]. analyst,2014.
APA Chen, Lisha,Chang, Fengxia,Meng, Lingchen,Li, Meixian,&Zhu, Zhiwei.(2014).A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry.analyst.
MLA Chen, Lisha,et al."A novel electrochemical chiral sensor for 3,4-dihydroxyphenylalanine based on the combination of single-walled carbon nanotubes, sulfuric acid and square wave voltammetry".analyst (2014).
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