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	分子连接性指数与溶液吸附自由能的相关性; THE RELATIONSHIP OF MOLECULAR CONNECTIVITY INDES TO CHANGES OF STANDARD FREE-ENERGY IN ADSORPTION PROCESSES
	赵振国
	1995
关键词	分子连接性指数 吸附标准自由能 自溶液中的吸附
英文摘要	测定了硅胶自四氯化碳中吸附脂肪醇及活性炭自水中吸附芳香化合物的吸附等温线,等温线均可用Langmuir方程描述.利用Langmuir参数计算了各体系的吸附标准自由能变化.计算了各种吸附质的分子连接性指数.各种分子的分子连接性指数与吸附标准自由能变化间有相关性,并给出了相关方程,同时作了初步的讨论.; The adsorption isotherms of aliphatic alcohols from carbon tetrachloride onto silica gel, of some aromatic compounds from water onto active carbon have been determined. The isotherms can be represented by the Langmuir equation. The changes of standard free energy (Delta G(0)) in adsorption processes have been calculated from the Langmuir parameters. The relationship of the molecular connectivity index to the Delta G(0) was tested. The results show, that the molecular connectivity model is a accurate predictive tool for the adsorption properties of organic compounds in the certain condition.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:A1995RL62200007&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科学引文数据库(CSCD); 1; 06; 557-562; 53
语种	中文
出处	知网 ; SCI
出版者	化学学报
内容类型	其他
源URL	[http://hdl.handle.net/20.500.11897/81157]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	赵振国. 分子连接性指数与溶液吸附自由能的相关性, THE RELATIONSHIP OF MOLECULAR CONNECTIVITY INDES TO CHANGES OF STANDARD FREE-ENERGY IN ADSORPTION PROCESSES. 1995-01-01.

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