QQ客服 官方微博 反馈留言

	四(4-重氮基苯基)卟啉的合成及其与聚苯乙烯磺酸钠自组装的研究; Synthesis of tetra (4-diazoniumbenzene)porphyrin and the self-assembled film with poly(styrene sulfonate)
	张茂峰 ; 江玮 ; 杨朝晖 ; 曹维孝
	2004
关键词	四(4-重氮基苯基)卟啉 聚苯乙烯磺酸钠 自组装膜 tetra (4-diazoniumbenzene)porphyrin poly(styrene sulfonate) self-assemblly film
英文摘要	Tetra(4-diazoniumbenzene)porphyrin(TDBP) was synthesized via diazo-reaction of tetra-(4-aminobenzene)porphyrin(TABP). From the analysis results of MALDI-TOF mass spectroscopy and FTIR,it was confirmed that the synthesized porphyrin derivative mainly consists of tetra(4-diazoniumbenzene) porphyrin wi...; Tetra (4-diazoniumbenzene) porphyrin (TDBP) was synthesized via diazo-reaction of tetra-(4-aminobenzene) porphyrin (TABP). From the analysis results of MALDI-TOF mass spectroscopy and FTIR, it was confirmed that the synthesized porphyrin derivative mainly consists of tetra (4-diazoniumbenzene) porphyrin with trace tri- and di-substituted compounds. The self-assembly of TDBP with poly (styrene sulfonate) (PSS) was carried out and a novel TDBP/PSS multilayer ultrathin film on silicon substrate was obtained. The self-assembled film is very sensitive to heat and light, after heating or irradiation of UV light, the thin film becomes very stable towards polar solvents such as DMF. The coupling reaction of TDBP with phenol and the thermal stability of TDBP were also investigated preliminary.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000222170400049&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 0; 06; 1180-1182; 25
语种	中文
出处	万方 ; 知网 ; SCI
出版者	高等学校化学学报
内容类型	其他
源URL	[http://hdl.handle.net/20.500.11897/80619]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	张茂峰,江玮,杨朝晖,等. 四(4-重氮基苯基)卟啉的合成及其与聚苯乙烯磺酸钠自组装的研究, Synthesis of tetra (4-diazoniumbenzene)porphyrin and the self-assembled film with poly(styrene sulfonate). 2004-01-01.

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。