聚酰胺-胺型树枝状化合物与四氯化钛的配合及其催化作用初步研究; PAMAM Dendritic Titanium Tetrachloride Complexes and Their Catalytic Reactivity | |
王金凤 ; 贾欣茹 ; 金钟 ; 张伟程 ; 范瑜 ; 李明谦 ; 危岩 | |
2001 | |
关键词 | 树枝状化合物 配合 四氯化钛 α-甲基苯乙烯 dendrimer complex titanium tetrachloride alpha-methyl styrene |
英文摘要 | The modification of PAMAM(G=3.0) dendrimers was achieved by using aldehyde, benzyl chloride and trityl chloride as reaction agents, respectively. The complexes were synthesized simply by dropping TiCl4 solution into the modified PAMAM dendrimers that were dissolved in certain solvent. The quantity of Ti contained in the complexes increased as the adding amount of TiCl4 was increased. The polymerization of α-methyl styrene catalyzed by the complexes was accomplished and it has shown that the complexes possessed catalytic function.; The modification of PAMAM(G=3.0) dendrimers was achieved by using aldehyde, benzyl chloride and trityl chloride as reaction agents, respectively. The complexes were synthesized simply by dropping TiCl4 solution into the modified PAMAM dendrimers that were dissolved in certain solvent. The quantity of Ti contained in the complexes increased as the adding amount of TiCl4 was increased. The polymerization of α-methyl styrene catalyzed by the complexes was accomplished and it has shown that the complexes possessed catalytic function.; 国家自然科学基金; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000168362300053&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); EI; 中文核心期刊要目总览(PKU); 中国科学引文数据库(CSCD); 2; 4; 709-711; 22 |
语种 | 中文 |
出处 | 万方 ; SCI ; http://d.g.wanfangdata.com.cn/Periodical_gdxxhxxb200104053.aspx |
出版者 | 高等学校化学学报 |
内容类型 | 其他 |
源URL | [http://hdl.handle.net/20.500.11897/80362] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | 王金凤,贾欣茹,金钟,等. 聚酰胺-胺型树枝状化合物与四氯化钛的配合及其催化作用初步研究, PAMAM Dendritic Titanium Tetrachloride Complexes and Their Catalytic Reactivity. 2001-01-01. |
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