Preparation of poly(vinyl alcohol)-based separator with pore-forming additive for lithium-ion batteries | |
Xiao, Wei; Zhang, Kaiyue; Liu, Jianguo; Yan, Chuanwei; Xiao, W (reprint author), Chinese Acad Sci, Inst Met Res, Lab Corros & Protect, Shenyang 110016, Liaoning, Peoples R China. | |
刊名 | SPRINGER |
2017-12-01 | |
卷号 | 28期号:23页码:17516-17525 |
ISSN号 | 0957-4522 |
英文摘要 | In this work, poly(vinyl alcohol) (PVA)-based separators with microporous structure were prepared from a casting solution composed of PVA resin, water as solvent, and poly(vinyl pyrrolidone) (PVP) polymer as pore controlling additive by non-solvent induced phase separation (NIPS) wet-process and investigated in lithium-ion batteries. The effects of PVP on the morphology and properties of the separator, such as porosity, electrolyte wettability, thermal stability and battery performance (discharge capacity, C-rate capability and cycleability) were systematically analyzed. Results show that PVP induced more pores on the bottom surfaces and the electrolyte uptake, ionic conductivity was further improved. Finally, a 10 wt% PVA-based separator with PVP solid content of 6 wt% exhibited greatly improved porosity, electrolyte uptake, ion conductivity and thermal resistance, resulting in the cell with high safety performance and matched electrochemical performance. The results demonstrated that the PVA-based separator with PVP as pore controlling additive can be a successful candidate serving as an effective separator for lithium-ion battery. Additionally, the present method of producing the microporous separator for LIBs is simple, environmentally benign and economically viable.; In this work, poly(vinyl alcohol) (PVA)-based separators with microporous structure were prepared from a casting solution composed of PVA resin, water as solvent, and poly(vinyl pyrrolidone) (PVP) polymer as pore controlling additive by non-solvent induced phase separation (NIPS) wet-process and investigated in lithium-ion batteries. The effects of PVP on the morphology and properties of the separator, such as porosity, electrolyte wettability, thermal stability and battery performance (discharge capacity, C-rate capability and cycleability) were systematically analyzed. Results show that PVP induced more pores on the bottom surfaces and the electrolyte uptake, ionic conductivity was further improved. Finally, a 10 wt% PVA-based separator with PVP solid content of 6 wt% exhibited greatly improved porosity, electrolyte uptake, ion conductivity and thermal resistance, resulting in the cell with high safety performance and matched electrochemical performance. The results demonstrated that the PVA-based separator with PVP as pore controlling additive can be a successful candidate serving as an effective separator for lithium-ion battery. Additionally, the present method of producing the microporous separator for LIBs is simple, environmentally benign and economically viable. |
学科主题 | Engineering, Electrical & Electronic ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
语种 | 英语 |
资助机构 | National Science Foundation of China [21676282, 21373009] |
公开日期 | 2018-01-10 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/78957] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Xiao, W (reprint author), Chinese Acad Sci, Inst Met Res, Lab Corros & Protect, Shenyang 110016, Liaoning, Peoples R China. |
推荐引用方式 GB/T 7714 | Xiao, Wei,Zhang, Kaiyue,Liu, Jianguo,et al. Preparation of poly(vinyl alcohol)-based separator with pore-forming additive for lithium-ion batteries[J]. SPRINGER,2017,28(23):17516-17525. |
APA | Xiao, Wei,Zhang, Kaiyue,Liu, Jianguo,Yan, Chuanwei,&Xiao, W .(2017).Preparation of poly(vinyl alcohol)-based separator with pore-forming additive for lithium-ion batteries.SPRINGER,28(23),17516-17525. |
MLA | Xiao, Wei,et al."Preparation of poly(vinyl alcohol)-based separator with pore-forming additive for lithium-ion batteries".SPRINGER 28.23(2017):17516-17525. |
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