Formation of porous Cu hydroxy double salt nanoflowers derived from metal-organic frameworks with efficient peroxidase-like activity for label-free detection of glucose | |
Li, AL; Mu, XJ; Li, TR; Wen, H1; Li, WC; Li, YE; Wang, BD | |
刊名 | NANOSCALE |
2018-07-07 | |
卷号 | 10期号:25页码:11948-11954 |
ISSN号 | 2040-3364 |
DOI | 10.1039/c8nr02832j |
英文摘要 | Currently, nanomaterials with peroxidase activity have become an important colorimetric tool for biomolecular detection. However, compared with natural enzymes, the efficiency of most nanozymes is still lower. Here, with a leaf-like metal-organic-framework-5 as both a precursor and a template and copper acetate as a second precursor, hierarchical Cu hydroxy double salt (HDS) nanoflowers have been prepared and used as a label-free glucose colorimetric detection platform. We have demonstrated a scalable and facile synthesis of hierarchical Cu HDS nanoflowers, and density functional theory (DFT) calculations confirmed that there exists a hydrogen bond between the terephthalate anions and the layer OH group. The composition of Cu hydroxyl double salt is [Cu-4(OH)(6)][BDC] |
学科主题 | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
语种 | 英语 |
WOS记录号 | WOS:000437761500026 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/80103] |
专题 | 金属研究所_中国科学院金属研究所 |
作者单位 | 1.Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China 3.Lanzhou Univ, Sch Informat Sci & Engn, Lanzhou 730000, Gansu, Peoples R China 4.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Li, AL,Mu, XJ,Li, TR,et al. Formation of porous Cu hydroxy double salt nanoflowers derived from metal-organic frameworks with efficient peroxidase-like activity for label-free detection of glucose[J]. NANOSCALE,2018,10(25):11948-11954. |
APA | Li, AL.,Mu, XJ.,Li, TR.,Wen, H.,Li, WC.,...&Wang, BD.(2018).Formation of porous Cu hydroxy double salt nanoflowers derived from metal-organic frameworks with efficient peroxidase-like activity for label-free detection of glucose.NANOSCALE,10(25),11948-11954. |
MLA | Li, AL,et al."Formation of porous Cu hydroxy double salt nanoflowers derived from metal-organic frameworks with efficient peroxidase-like activity for label-free detection of glucose".NANOSCALE 10.25(2018):11948-11954. |
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