Selectively biorefining levoglucosan from NaOH pretreated corncobs via fast pyrolysis | |
Jiang, Liqun; Wu, Yaxiang; Zhao, Zengli; Li, Haibin; Zhao, Kun; Zhang, Fan1 | |
刊名 | CELLULOSE |
2019 | |
卷号 | 26期号:13-14页码:7877-7887 |
关键词 | Biomass Alkali pretreatment Fast pyrolysis Levoglucosan |
ISSN号 | 0969-0239 |
DOI | 10.1007/s10570-019-02625-4 |
英文摘要 | Fast pyrolysis is a comparable technology with enzyme or acid hydrolysis for saccharification of biomass. The low yield of levoglucosan and the formation of inhibitors to biocatalysts from lignocellulose hamper the fermentable utilization of pyrolysate. In this study, aiming to enhance the production of levoglucosan, dilute alkali pretreatment was performed prior to fast pyrolysis of corncobs. The yield of levoglucsoan from pretreated corncobs was significantly improved (34.8%) as compared to that from un-treated corncobs (3.0%), which was mainly attributed to the removal of alkaline and alkaline earth metals as well as lignin fraction by NaOH pretreatment. Conversely, NaOH pretreatment suppressed the formation of acids (from 11.1 to 2.2%), furans (from 2.5 to 2.0%), ketones (from 15.7 to 9.8%) and phenols (from 4.8 to 1.3%), which were common inhibitors to the biocatalysts. Accordingly, NaOH pretreatment facilitated further selective conversion of biomass in fast pyrolysis and made the pyrolysate more fermentable. [GRAPHICS] . |
学科主题 | Materials Science ; Polymer Science |
语种 | 英语 |
WOS记录号 | WOS:000483695400021 |
内容类型 | 期刊论文 |
源URL | [http://ir.xtbg.org.cn/handle/353005/11453] |
专题 | 西双版纳热带植物园_生物能源研究组 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, 2 Nengyuan Rd, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Biomass Grp, Key Lab Trop Plant Resources & Sustainable Use, Xishuangbanna Trop Bot Garden, 88 Xuefulu, Kunming 650223, Yunnan, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Liqun,Wu, Yaxiang,Zhao, Zengli,et al. Selectively biorefining levoglucosan from NaOH pretreated corncobs via fast pyrolysis[J]. CELLULOSE,2019,26(13-14):7877-7887. |
APA | Jiang, Liqun,Wu, Yaxiang,Zhao, Zengli,Li, Haibin,Zhao, Kun,&Zhang, Fan.(2019).Selectively biorefining levoglucosan from NaOH pretreated corncobs via fast pyrolysis.CELLULOSE,26(13-14),7877-7887. |
MLA | Jiang, Liqun,et al."Selectively biorefining levoglucosan from NaOH pretreated corncobs via fast pyrolysis".CELLULOSE 26.13-14(2019):7877-7887. |
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