New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel

doi:10.1016/j.elecom.2018.07.013

CORC > 高能物理研究所 > 中国科学院高能物理研究所 > 核技术应用研究中心

	New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel
	Zhang, ML; Wang, P; Zhang, YM; Ji, DB; Yan, YD; Shi, WQ; Huang, Q; Du, SY; Shi WQ(石伟群)
刊名	ELECTROCHEMISTRY COMMUNICATIONS
	2018
卷号	93 页码:180-182
关键词	Bimodal effect Reduction potential Atomic radius difference Electronegativity difference Hume-Rothery's rules
ISSN号	1388-2481
DOI	10.1016/j.elecom.2018.07.013
文献子类	Article
英文摘要	In this work, the electrochemical behavior of lanthanides (except promethium) on several active cathodes in LiCl-KCl molten salts was investigated. We have discovered that the reduction potentials of lanthanide alloys present a "bimodal effect". A numerical model was established based on the result of multiple linear regression analyses, which indicates that the reduction potentials are correlated with differences in atomic radii and differences in electronegativity. Employing the fitted formulae, which provide a preliminary model of the behavior of these elements in electrolysis-based pyroprocessing, the electrochemistry of both lanthanides and actinides on active metal cathodes could be reasonably estimated.
电子版国际标准刊号	1873-1902
WOS关键词	MOLTEN-SALT ; ELECTRONEGATIVITY ; ELECTRODES ; ENERGY
WOS研究方向	Electrochemistry
语种	英语
WOS记录号	WOS:000439858800039
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/286151]
专题	高能物理研究所_核技术应用研究中心高能物理研究所_多学科研究中心
通讯作者	Shi WQ(石伟群)
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Zhang, ML,Wang, P,Zhang, YM,et al. New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel[J]. ELECTROCHEMISTRY COMMUNICATIONS,2018,93:180-182.
APA	Zhang, ML.,Wang, P.,Zhang, YM.,Ji, DB.,Yan, YD.,...&石伟群.(2018).New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel.ELECTROCHEMISTRY COMMUNICATIONS,93,180-182.
MLA	Zhang, ML,et al."New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel".ELECTROCHEMISTRY COMMUNICATIONS 93(2018):180-182.