Cation vacancy stabilization of single-atomic-site Pt-1/Ni(OH)(x) catalyst for diboration of alkynes and alkenes

doi:10.1038/s41467-018-03380-z

	Cation vacancy stabilization of single-atomic-site Pt-1/Ni(OH)(x) catalyst for diboration of alkynes and alkenes
	Zheng LR(郑黎荣); Zhang, J; Wu, X; Cheong, WC; Chen, WX; Lin, R; Li, J; Li, YD; Zheng, LR; Yan, WS
刊名	NATURE COMMUNICATIONS
	2018
卷号	9 页码:1002
ISSN号	2041-1723
DOI	10.1038/s41467-018-03380-z
文献子类	Article
英文摘要	Development of single-atomic-site catalysts with high metal loading is highly desirable but proved to be very challenging. Although utilizing defects on supports to stabilize independent metal atoms has become a powerful method to fabricate single-atomic-site catalysts, little attention has been devoted to cation vacancy defects. Here we report a nickel hydroxide nanoboard with abundant Ni2+ vacancy defects serving as the practical support to achieve a single-atomic-site Pt catalyst (Pt-1/Ni(OH)(x)) containing Pt up to 2.3 wt% just by a simple wet impregnation method. The Ni2+ vacancies are found to have strong stabilizing effect of single-atomic Pt species, which is determined by X-ray absorption spectrometry analyses and density functional theory calculations. This Pt-1/Ni(OH)(x) catalyst shows a high catalytic efficiency in diboration of a variety of alkynes and alkenes, yielding an overall turnover frequency value upon reaction completion for phenylacetylene of similar to 3000 h(-1), which is much higher than other reported heterogeneous catalysts.
WOS关键词	NICKEL-HYDROXIDE NANORIBBONS ; CO OXIDATION ; PLATINUM NANOPARTICLES ; FORMIC-ACID ; SURFACE ; OXYGEN ; GOLD ; HYDROGENATION ; GRAPHENE ; CLUSTERS
WOS研究方向	Science & Technology - Other Topics
语种	英语
WOS记录号	WOS:000427007700011
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/285713]
专题	高能物理研究所_多学科研究中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Zheng LR,Zhang, J,Wu, X,et al. Cation vacancy stabilization of single-atomic-site Pt-1/Ni(OH)(x) catalyst for diboration of alkynes and alkenes[J]. NATURE COMMUNICATIONS,2018,9:1002.
APA	郑黎荣.,Zhang, J.,Wu, X.,Cheong, WC.,Chen, WX.,...&Wang, DS.(2018).Cation vacancy stabilization of single-atomic-site Pt-1/Ni(OH)(x) catalyst for diboration of alkynes and alkenes.NATURE COMMUNICATIONS,9,1002.
MLA	郑黎荣,et al."Cation vacancy stabilization of single-atomic-site Pt-1/Ni(OH)(x) catalyst for diboration of alkynes and alkenes".NATURE COMMUNICATIONS 9(2018):1002.