Excited-State Modulation for Controlling Fluorescence and Phosphorescence Pathways toward White-Light Emission | |
Feng, Changfu; Li, Shuai; Xiao, Xiaoxiao; Lei, Yilong; Geng, Hua; Liao, Yi; Liao, Qing; Yao, Jiannian; Wu, Yishi; Fu, Hongbing | |
刊名 | ADVANCED OPTICAL MATERIALS |
2019-08-02 | |
ISSN号 | 2195-1071 |
DOI | 10.1002/adom.201900767 |
英文摘要 | Luminescence originated from singlet (S-1) and triplet (T-1) states is categorized as fluorescence and phosphorescence, respectively. Modulation of fluorescence and phosphorescence pathways plays a central role in developing organic luminescent materials, but remains difficult because of the lack of control ways. Here, luminescence of cocrystals of 1,7-phenanthroline (PR) and 1,4-diiodotetrafluorobenzene (DITFB) can be switched by adjusting their stoichiometry, from bluish fluorescence for 1:0 pure PR crystal (P1D0) to yellowish phosphorescence for 1:1 PR:DITFB cocrystal (P1D1). More importantly, 2:1 PR:DITFB cocrystal (P2D1) is found to exhibit dual fluorescence and phosphorescence simultaneously, thus giving rise to white-light emission. Experimental and time-dependent density-function-theory results reveal that although the S-1 and T-1 energies keep invariable, high-lying T-n states introduced in cocrystals decreases the S-1-T-n energy gap, meanwhile multiple intermolecular halogen bonding enhances the spin-orbital coupling. As a result, the S-1 -> T-n intersystem crossing rate (k(ISC)) is accelerated by 2 orders of magnitude, making k(ISC) comparable and faster than the fluorescence decay rate k(Fl) for P1D0 (fluorescence), P2D1 (dual emissions), and P1D1 (phosphorescence), respectively. The results provide not only a quantum-mechanical understanding but also a novel strategy to modulate the excited-state dynamics toward fluorescence and/or phosphorescence emissions for luminescent materials. |
语种 | 英语 |
WOS记录号 | WOS:000478972200001 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/82686] |
专题 | 中国科学院化学研究所 |
作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Feng, Changfu,Li, Shuai,Xiao, Xiaoxiao,et al. Excited-State Modulation for Controlling Fluorescence and Phosphorescence Pathways toward White-Light Emission[J]. ADVANCED OPTICAL MATERIALS,2019. |
APA | Feng, Changfu.,Li, Shuai.,Xiao, Xiaoxiao.,Lei, Yilong.,Geng, Hua.,...&Fu, Hongbing.(2019).Excited-State Modulation for Controlling Fluorescence and Phosphorescence Pathways toward White-Light Emission.ADVANCED OPTICAL MATERIALS. |
MLA | Feng, Changfu,et al."Excited-State Modulation for Controlling Fluorescence and Phosphorescence Pathways toward White-Light Emission".ADVANCED OPTICAL MATERIALS (2019). |
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