Study on synthesis of 2-Amino-2 '-hydroxy-1,1 '-binaphthyl by two-phase oxidative coupling with a cyclic solid oxidant

	Study on synthesis of 2-Amino-2 '-hydroxy-1,1 '-binaphthyl by two-phase oxidative coupling with a cyclic solid oxidant
	Jiang, Y ; Wang, JY ; Chen, JH ; Wang, WJ ; Yan, H ; Zhang, XX ; Wang, C ; Zhang, GL ; Li, BG
刊名	ACTA CHIMICA SINICA
	2007
卷号	65 期号:17 页码:1925_1928
关键词	2-naphthol 2-naphthylarmine solid-oxidant cross-coupling 2-amino-2 '-hydroxy-1 1 '-binaphthyl
ISSN号	0567-7351
其他题名	可循环利用的固体氧化剂两相氧化偶联合成2-氨基-2'-羟基-1,1'-联萘的研究
通讯作者	Jiang, Y, Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China.
产权排序	2
中文摘要	Various solid-oxidants with different loadings of FeCl3 on Al2O3 were prepared by impregnation. The effects of support and solvent on the oxidative cross-coupling of 2-naphthol with 2-naphthylamine using FeCl3/Al2O3 were studied. Up to 95.01% yield of 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN) was obtained in chlorobenzene using the oxidant with 10% FeCl3 loading on the support containing 5% TiO2 at 60 degrees C. The activity of the used oxidant was improved by treatment with H2O2, which provided an effective method to regenerate the solid-oxidant.
学科主题	Chemistry, Multidisciplinary
收录类别	SCI
语种	中文
WOS记录号	WOS:000249894200034
公开日期	2011-07-08
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/17979]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Jiang, Y,Wang, JY,Chen, JH,et al. Study on synthesis of 2-Amino-2 '-hydroxy-1,1 '-binaphthyl by two-phase oxidative coupling with a cyclic solid oxidant[J]. ACTA CHIMICA SINICA,2007,65(17):1925_1928.
APA	Jiang, Y.,Wang, JY.,Chen, JH.,Wang, WJ.,Yan, H.,...&Li, BG.(2007).Study on synthesis of 2-Amino-2 '-hydroxy-1,1 '-binaphthyl by two-phase oxidative coupling with a cyclic solid oxidant.ACTA CHIMICA SINICA,65(17),1925_1928.
MLA	Jiang, Y,et al."Study on synthesis of 2-Amino-2 '-hydroxy-1,1 '-binaphthyl by two-phase oxidative coupling with a cyclic solid oxidant".ACTA CHIMICA SINICA 65.17(2007):1925_1928.