Strong damping of the localized surface plasmon resonance of Ag nanoparticles by Ag2O
Wu, Qingmen1; Si, Mengting1; Zhang, Bing1; Zhang, Kang1; Li, Huanhuan1; Mi, Longfei2; Jiang, Yang2; Rong, Yan3; Chen, Junling3; Fang, Yingcui1
刊名NANOTECHNOLOGY
2018-07-20
卷号29期号:29页码:10
关键词oxidation of silver nanoparticles decomposition of silver oxide annealing strong damping of localized surface plasmon resonance oxygen plasma irradiation
ISSN号0957-4484
DOI10.1088/1361-6528/aac031
英文摘要

By studying oxidation of AgNPs (Ag nanoparticles) and decomposition of the produced silver oxide, we demonstrate that the localized surface plasmon resonance (LSPR) of AgNPs was damped by Ag2O produced during oxygen plasma irradiation (OPI). The AgNPs were fabricated by evaporation of high pure silver under high vacuum. The oxidation was conducted in oxygen plasma generated by radio frequency glow discharging in vacuum, and the decomposition was performed by annealing the silver oxide in nitrogen ambient at temperatures ranging from room temperature to 450 degrees C. Samples were characterized by color, absorption spectra, surface enhanced Raman scattering, x-ray photoelectron spectroscopy, and field emission scanning electron microscopy. The bandgap of the silver oxide was calculated. We propose that AgNPs are only partially oxidized into silver oxide during OPI, and the LSPR of the AgNPs left without being oxidation is strongly damped by the produced silver oxide. This LSPR damping is responsible for the transparency of the sample after OPI for 2 s.

资助项目National Natural Science Foundation of China[11674081] ; Natural Science Foundation of Anhui Province of China[1708085MA11]
WOS关键词OXIDE THIN-FILMS ; OPTICAL-PROPERTIES ; PHOTOCATALYTIC ACTIVITY ; THERMAL-DECOMPOSITION ; CHARGE-TRANSFER ; SILVER SURFACE ; OXYGEN ; OXIDATION ; HETEROSTRUCTURES ; SPECTROSCOPY
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者IOP PUBLISHING LTD
WOS记录号WOS:000432431800002
内容类型期刊论文
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/36794]  
专题合肥物质科学研究院_中科院等离子体物理研究所
通讯作者Fang, Yingcui
作者单位1.Hefei Univ Technol, Dept Vacuum Sci & Technol, Hefei 230009, Anhui, Peoples R China
2.Hefei Univ Technol, Dept Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
3.Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Wu, Qingmen,Si, Mengting,Zhang, Bing,et al. Strong damping of the localized surface plasmon resonance of Ag nanoparticles by Ag2O[J]. NANOTECHNOLOGY,2018,29(29):10.
APA Wu, Qingmen.,Si, Mengting.,Zhang, Bing.,Zhang, Kang.,Li, Huanhuan.,...&Fang, Yingcui.(2018).Strong damping of the localized surface plasmon resonance of Ag nanoparticles by Ag2O.NANOTECHNOLOGY,29(29),10.
MLA Wu, Qingmen,et al."Strong damping of the localized surface plasmon resonance of Ag nanoparticles by Ag2O".NANOTECHNOLOGY 29.29(2018):10.
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