BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet

doi:10.1002/open.201700041

	BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet
	Wang, ZM; Yang, DL; Gao ZQ(高增强); Zhu, DB; Guo, YJ; Wang, DW; Zhang, B; Zhang, Y; Gao, ZQ
刊名	CHEMISTRYOPEN
	2017
卷号	6 期号:3 页码:320-324
关键词	antiferromagnetism cation templates charge-transfer salts Jahn-Teller distortion square lattices
ISSN号	2191-1363
DOI	10.1002/open.201700041
文献子类	Article
英文摘要	A dual-functional organic-inorganic hybrid (BEDTTTF) Cu-2(2)( HCOO) 5 ( 1) (BEDT-TTF=bis(ethylenedithio) tetrathiafulvalene) was obtained through the electrochemical oxidation of neutral BEDT-TTF in the presence of an ammonium salt of the one-dimensional copper- formate framework [(C2H5)(3)NH](2)Cu-2(HCOO)(5) in a C6H5Cl-C2H5OH solution. Compound 1 was composed of organic donor BEDT-TTF+0.5 in a qphase arrangement and Jahn- Teller distorted (4,4) grid anion sheets [Cu-2(HCOO)(5)-]n with S=1/2. We identified the material as a semiconductor with values of sigma 300K= 10(-1) Scm(-1). The anion sheet is a coordination isomer of [Cu-2(HCOO)(5)(-)](n) and, compared with the starting material, shows antiferromagnetic behavior as the well-known inorganic Cu-O, Co-O square layers for creating inorganic conducting magnets. Long-range antiferromagnetic ordering was observed at 8.0 K.
WOS关键词	SQUARE HEISENBERG-ANTIFERROMAGNET ; THEORETICAL CHARACTERIZATION ; CRYSTAL-STRUCTURE ; MOLECULAR-METAL ; COPPER FORMATE ; LATTICE ; SUPERCONDUCTIVITY ; TRANSITION ; PEROVSKITE ; FRAMEWORK
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000403801800003
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/285222]
专题	高能物理研究所_多学科研究中心高能物理研究所_粒子天体物理中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Wang, ZM,Yang, DL,Gao ZQ,et al. BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet[J]. CHEMISTRYOPEN,2017,6(3):320-324.
APA	Wang, ZM.,Yang, DL.,高增强.,Zhu, DB.,Guo, YJ.,...&Gao, ZQ.(2017).BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet.CHEMISTRYOPEN,6(3),320-324.
MLA	Wang, ZM,et al."BEDT-TTF)(2)Cu-2(HCOO)(5): An Organic-Inorganic Hybrid Conducting Magnet".CHEMISTRYOPEN 6.3(2017):320-324.