Mo6+ activated multimetal oxygen-evolving catalysts

doi:10.1039/c6sc04819f

CORC > 高能物理研究所 > 中国科学院高能物理研究所 > 中国科学院高能物理研究所 > 中国散裂中子源

	Mo6+ activated multimetal oxygen-evolving catalysts
	Yang, HG; Zheng LR(郑黎荣); Zhang, B; Zheng, LR; Yang, S; Liu, PF
刊名	CHEMICAL SCIENCE
	2017
卷号	8 期号:5 页码:3484-3488
ISSN号	2041-6520
DOI	10.1039/c6sc04819f
文献子类	Article
英文摘要	Water splitting is key to electrically-powered chemical fuel synthesis, but the slow kinetics of the oxygen evolution reaction (OER) hinder the wider promotion of such technology. Several first-row (3d) transition metal-based catalysts have been developed for the OER; however, these catalysts still require operating voltages that lie well above the fundamental thermodynamic potential. Here, we report high-valence metal molybdenum (Mo6+) modulated 3d metal (oxy) hydroxides. The obtained multimetal FeCoMo based OER catalysts require an overpotential of 277 mV to reach the current density of 10 mA cm(-2) on the glassy carbon electrode, and there was no evidence of degradation for about 40 hours of stability testing. The catalysts stay in their amorphous phases, potentially with atomically homogenous metal distribution. The in situ X-ray adsorption analysis unambiguously reveals the tuned electronic structures of the 3d metals owing to Mo6+, further demonstrating the modification effect of a high-valence metal for designing highly-efficient OER catalysts.
电子版国际标准刊号	2041-6539
WOS关键词	WATER OXIDATION CATALYSIS ; EVOLUTION CATALYSTS ; REDUCTION REACTION ; NICKEL-HYDROXIDE ; COBALT ; IRON ; ELECTROCATALYSTS ; TRANSITION ; PHOSPHATE ; SPECTROSCOPY
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000400553000021
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/285198]
专题	中国科学院高能物理研究所_中国散裂中子源高能物理研究所_粒子天体物理中心高能物理研究所_多学科研究中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Yang, HG,Zheng LR,Zhang, B,et al. Mo6+ activated multimetal oxygen-evolving catalysts[J]. CHEMICAL SCIENCE,2017,8(5):3484-3488.
APA	Yang, HG,郑黎荣,Zhang, B,Zheng, LR,Yang, S,&Liu, PF.(2017).Mo6+ activated multimetal oxygen-evolving catalysts.CHEMICAL SCIENCE,8(5),3484-3488.
MLA	Yang, HG,et al."Mo6+ activated multimetal oxygen-evolving catalysts".CHEMICAL SCIENCE 8.5(2017):3484-3488.