Zinc-modulated Fe-Co Prussian blue analogues with well-controlled morphologies for the efficient sorption of cesium

doi:10.1039/c6ta10016c

	Zinc-modulated Fe-Co Prussian blue analogues with well-controlled morphologies for the efficient sorption of cesium
	Fan, QH; Xu, W; Cong, WM; Jin, CZ; Tang, HL; Xu W(徐伟); Wang, JH; Wang, XD; Ge, RL; Ganeshraja, AS
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2017
卷号	5 期号:7 页码:3284-3292
ISSN号	2050-7488
DOI	10.1039/c6ta10016c
文献子类	Article
英文摘要	Prussian blue analogues (PBAs) with tunable compositions and morphologies have demonstrated great potential in many applications. We successfully synthesized a series of KFexZn1-x[Co(CN)6] (FexZn1-x-Co) PBAs with well-controlled compositions and morphologies and used them as adsorbents for the removal of Cs+ ions. The increase of Zn : Fe ratio had a significant influence on the final morphology and improved the sorption capacity for Cs. X-ray diffraction and X-ray absorption fine structure spectra were used to confirm that the Cs+ ions were inserted into the crystal channels rather than simply adsorbed on the surface of the PBAs. Based on the quantitative correlation between the concentration of ions released from the PBAs and the Cs+ ions adsorbed, the mechanism of Cs+ sorption in the FexZn1-x-Co PBAs was studied and a Zn2+-modulated Cs+ sorption model, which illustrated the difference in sorption behavior between the FexZn1-x-Co PBAs, was proposed and confirmed by FTIR spectra, extended X-ray absorption fine structure spectra and Fe-57 Mossbauer spectra. The results indicated that the FexZn1-x-Co PBAs are excellent candidates for the removal of radioactive Cs-137 from nuclear waste.
电子版国际标准刊号	2050-7496
WOS关键词	RAY-ABSORPTION SPECTROSCOPY ; SHAPE-CONTROLLED SYNTHESIS ; RADIOACTIVE CESIUM ; HIGHLY EFFICIENT ; METAL CYANIDES ; ADSORPTION ; CATALYSTS ; WATER ; REMOVAL ; OXIDE
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
语种	英语
WOS记录号	WOS:000395077600026
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/285172]
专题	高能物理研究所_实验物理中心高能物理研究所_多学科研究中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Fan, QH,Xu, W,Cong, WM,et al. Zinc-modulated Fe-Co Prussian blue analogues with well-controlled morphologies for the efficient sorption of cesium[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(7):3284-3292.
APA	Fan, QH.,Xu, W.,Cong, WM.,Jin, CZ.,Tang, HL.,...&Rykov, AI.(2017).Zinc-modulated Fe-Co Prussian blue analogues with well-controlled morphologies for the efficient sorption of cesium.JOURNAL OF MATERIALS CHEMISTRY A,5(7),3284-3292.
MLA	Fan, QH,et al."Zinc-modulated Fe-Co Prussian blue analogues with well-controlled morphologies for the efficient sorption of cesium".JOURNAL OF MATERIALS CHEMISTRY A 5.7(2017):3284-3292.