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Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation
Wang, Y; Wang, BS; Shen, JS
刊名JOURNAL OF APPLIED POLYMER SCIENCE
2004-05-15
卷号92期号:4页码:2593-2598
关键词Block Copolymers Strain Kinetics (Polym.) Mechanical Properties Structure Healing
ISSN号0021-8995
DOI10.1002/app.20235
英文摘要The kinetic mechanism of structure healing after unloading from large elongation for styrene-butadiene-styrene (SBS) block copolymer materials was investigated by following their residual deformation recovery behaviors upon annealing. A linear relationship was found to exist between the deformation recovery percentage and the logarithm of time at different temperatures, which shed light on the mechanism of structure healing. A modified activation energy model was proposed to describe the kinetics of the process. It was also found that the model agrees well with other SBS structure healing-related experimental data such as the recovery of hardness as well as dynamic mechanical property after large elongation. (C) 2004 Wiley Periodicals, Inc.
语种英语
出版者JOHN WILEY & SONS INC
WOS记录号WOS:000220435200067
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/81529]  
专题中国科学院化学研究所
通讯作者Wang, Y
作者单位1.Harbin Inst Technol, Mat Phys & Chem Dept, Harbin 150001, Peoples R China
2.Harbin Inst Technol, Sch Municipal & Environm Engn, Harbin 150001, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
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Wang, Y,Wang, BS,Shen, JS. Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2004,92(4):2593-2598.
APA Wang, Y,Wang, BS,&Shen, JS.(2004).Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation.JOURNAL OF APPLIED POLYMER SCIENCE,92(4),2593-2598.
MLA Wang, Y,et al."Investigation on the kinetic mechanism of structure healing for block copolymer materials after large elongation".JOURNAL OF APPLIED POLYMER SCIENCE 92.4(2004):2593-2598.
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