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Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate
Liu, Z; Yu, WT; Fang, Q; Jiang, MH; Zhang, DQ; Xu, CY; Zhu, DB
刊名SYNTHETIC METALS
2003-04-04
卷号135期号:1-3页码:699-700
关键词Electrocrystallization Single-crystal Growth Organic COnductors Based On Radical catiOn Salts X-ray Diffraction Conductivity
ISSN号0379-6779
DOI10.1016/S0379-6779(02)00798-1
英文摘要Electrochemical oxidation of 3,4,3',4'-bis(ethylenedithio)-2,2',5,5'-tetrathiafulvalene (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)(2)(CH2=CH-CHZ-SO3).H2O. The crystal structure has been determined to be in orthorhombic crystal system, Pma2 space group. In the crystal of the title compound, ET cations adopt a alpha'-type packing pattern and organic counter anions form infinite chains by hydrogen bonds along the c-axis. This salt is a semiconductor and its room-temperature conductivity is 0.0489 Omega(-1) m(-1).
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000182533700329
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/81253]  
专题中国科学院化学研究所
通讯作者Jiang, MH
作者单位1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Liu, Z,Yu, WT,Fang, Q,et al. Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate[J]. SYNTHETIC METALS,2003,135(1-3):699-700.
APA Liu, Z.,Yu, WT.,Fang, Q.,Jiang, MH.,Zhang, DQ.,...&Zhu, DB.(2003).Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate.SYNTHETIC METALS,135(1-3),699-700.
MLA Liu, Z,et al."Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate".SYNTHETIC METALS 135.1-3(2003):699-700.
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