Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate | |
Liu, Z; Yu, WT; Fang, Q; Jiang, MH; Zhang, DQ; Xu, CY; Zhu, DB | |
刊名 | SYNTHETIC METALS |
2003-04-04 | |
卷号 | 135期号:1-3页码:699-700 |
关键词 | Electrocrystallization Single-crystal Growth Organic COnductors Based On Radical catiOn Salts X-ray Diffraction Conductivity |
ISSN号 | 0379-6779 |
DOI | 10.1016/S0379-6779(02)00798-1 |
英文摘要 | Electrochemical oxidation of 3,4,3',4'-bis(ethylenedithio)-2,2',5,5'-tetrathiafulvalene (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)(2)(CH2=CH-CHZ-SO3).H2O. The crystal structure has been determined to be in orthorhombic crystal system, Pma2 space group. In the crystal of the title compound, ET cations adopt a alpha'-type packing pattern and organic counter anions form infinite chains by hydrogen bonds along the c-axis. This salt is a semiconductor and its room-temperature conductivity is 0.0489 Omega(-1) m(-1). |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000182533700329 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/81253] |
专题 | 中国科学院化学研究所 |
通讯作者 | Jiang, MH |
作者单位 | 1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Z,Yu, WT,Fang, Q,et al. Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate[J]. SYNTHETIC METALS,2003,135(1-3):699-700. |
APA | Liu, Z.,Yu, WT.,Fang, Q.,Jiang, MH.,Zhang, DQ.,...&Zhu, DB.(2003).Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate.SYNTHETIC METALS,135(1-3),699-700. |
MLA | Liu, Z,et al."Synthesis, structure and conductivity of di[3,4,3 ',4 '-bis(ethylenedithio)-2,2 ',5,5 '-tetrathiafulvalenium] allylsulfonate monohydrate".SYNTHETIC METALS 135.1-3(2003):699-700. |
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