Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O

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	Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O
	Shao, K ; Ma, Y ; Chen, ZH ; Zhang, XT ; He, T ; Yao, JN ; Liu, T ; Zhang, J ; Hu, TD
刊名	ACTA CHIMICA SINICA
	2001
卷号	59 期号:8 页码:1335-1339
关键词	Ethylenediammonium Molybdate Synthesis Photochromic Property
ISSN号	0567-7351
英文摘要	A novel photochromic compound NH3CH2CH2NH3Mo3O10.4.4H(2)O has been synthesized using ethylenediammonium cations as template under mild chemical conditions. Elemental analysis, TGA curve and IR spectra show that its inorganic framework is constructed from infinite chains of (Mo3O10)(infinity)(2-). Ethylenediammonium cations are bounded to the inorganic chain structure through a supramolecular interaction. It is found that this compound has good photochromic property. Differing from vacuum deposited MoO3 film, this compound turns from white to reddish brown after UV irradiation. EXAFS spectra confirm proton transfer from ethylenediammonium cations to Mo-O- after UV irradiation.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000170513100030
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/76861]
专题	中国科学院化学研究所
通讯作者	Shao, K
作者单位	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst High Energet Phys, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Shao, K,Ma, Y,Chen, ZH,et al. Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O[J]. ACTA CHIMICA SINICA,2001,59(8):1335-1339.
APA	Shao, K.,Ma, Y.,Chen, ZH.,Zhang, XT.,He, T.,...&Hu, TD.(2001).Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O.ACTA CHIMICA SINICA,59(8),1335-1339.
MLA	Shao, K,et al."Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O".ACTA CHIMICA SINICA 59.8(2001):1335-1339.