Synthesis, structure of a new acceptor TBA(2)S(6) and preparation, physical properties of ET3S6

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	Synthesis, structure of a new acceptor TBA(2)S(6) and preparation, physical properties of ET3S6
	Zhang, QC; Wu, PJ; Chen, SY; Ding, RS; Wang, YQ; Zhu, DB
刊名	SYNTHETIC METALS
	1999-09-15
卷号	105 期号:3 页码:155-159
关键词	Polysulphide Compound Crystal Structure Synthesis Organic Conductor Charge Transfer Physical Properties Bis(Ethylenedithio)Tetrathiofulvalene
ISSN号	0379-6779
英文摘要	A general procedure for the synthesis of the tetrabutylammoium hexasulphide, TBA(2)S(6), is first described. The structure of TBA(2)S(6) has been determined by X-ray crystallography. Lattice parameters and space group information are as follows: a = 15.039(5) Angstrom, b = 16.086(5) Angstrom, c = 17.078(6) Angstrom, alpha = beta = gamma = 90.00 degrees, V = 4131.5(24) Angstrom(3), orthorhombic, Pbnb (Z = 4). Diffraction data (MoKalpha radiation, 2 theta(max) = 50) is collected by Rigaku-AFC6 diffract meter. The structure was solved and refined by direct method and full-matrix least-squares procedures to R-value of 0.0645. The complex ET3S6 has been prepared through electrocrystallization ways. The conductivity of this salt at room temperature is 2.3 S cm(-1). It shows weak metallic behavior above 240 K. Below this temperature, it becomes a semiconductor. The XPS spectra indicated the presence of three different, kinds of S atoms in the salt. The ESR line width is found to be 44.478 G at room temperature. (C) 1999 Elsevier Science S.A. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE SA
WOS记录号	WOS:000082149400002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/75259]
专题	中国科学院化学研究所
通讯作者	Zhu, DB
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Zhang, QC,Wu, PJ,Chen, SY,et al. Synthesis, structure of a new acceptor TBA(2)S(6) and preparation, physical properties of ET3S6[J]. SYNTHETIC METALS,1999,105(3):155-159.
APA	Zhang, QC,Wu, PJ,Chen, SY,Ding, RS,Wang, YQ,&Zhu, DB.(1999).Synthesis, structure of a new acceptor TBA(2)S(6) and preparation, physical properties of ET3S6.SYNTHETIC METALS,105(3),155-159.
MLA	Zhang, QC,et al."Synthesis, structure of a new acceptor TBA(2)S(6) and preparation, physical properties of ET3S6".SYNTHETIC METALS 105.3(1999):155-159.