Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands

doi:10.1021/cg101610k

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	Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands
	Fu, Ying 1; Su, Jie 1; Yang, Sihai 2; Zou, Zhibo 3; Li, Guobao 1; Liao, Fuhui 1; Xiong, Ming 4; Lin, Jianhua 1
刊名	CRYSTAL GROWTH & DESIGN
	2011-06-01
卷号	11 期号:6 页码:2243-2249
ISSN号	1528-7483
DOI	10.1021/cg101610k
英文摘要	Three new compounds, [ZnNa(BTC)(H2O)(2)]center dot H2O (1), [Zn3Na2(BTC)(2)(HCOO)(2)(H2O)(8)] (2), and [Zn3Na(BTC)(2) (HCOO)(H2O)3]center dot H2O (3) (H3BTC = 1,3,5-benzenetricarboxylate acid), were synthesized under hydrothermal conditions and were characterized by the single crystal and powder X-ray diffraction, IR spectra, elemental analyses, ICP measurements, and coupled TG-MS analyses. 1, 2, and 3 crystallize in the space groups P (1) over bar, C2/c, and P1, respectively. They are three-dimensional (3D) frameworks, consisting of zigzag chains ((Na2Zn2O14)(n) for 1, (Na2Zn3O18)(n) for 2, or (NaZn3O14)(n) for 3) and bridging BTC ligands. Powder X-ray diffraction studies reveal that 1 and 2 exhibit reversible dehydration-rehydration behaviors with a crystal-to-crystal transformation observed for 2.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000291074600029
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/72859]
专题	中国科学院化学研究所
通讯作者	Li, Guobao
作者单位	1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China 2.Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England 3.Beijing Huiwen Middle Sch, Beijing 100061, Peoples R China 4.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China
推荐引用方式 GB/T 7714	Fu, Ying,Su, Jie,Yang, Sihai,et al. Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands[J]. CRYSTAL GROWTH & DESIGN,2011,11(6):2243-2249.
APA	Fu, Ying.,Su, Jie.,Yang, Sihai.,Zou, Zhibo.,Li, Guobao.,...&Lin, Jianhua.(2011).Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands.CRYSTAL GROWTH & DESIGN,11(6),2243-2249.
MLA	Fu, Ying,et al."Syntheses, Structures, and Structural Transformations of Mixed Na(I) and Zn(II) Metal-Organic Frameworks with 1,3,5-Benzenetricarboxylate Ligands".CRYSTAL GROWTH & DESIGN 11.6(2011):2243-2249.